Wavefunctions of fermions and bosons

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Homework Help Overview

The discussion revolves around the wavefunctions of two noninteracting particles in a cubical box, specifically focusing on the distinctions between fermions and bosons. The original poster presents a problem involving the construction of wavefunctions for distinguishable and identical particles, considering their spin states and the requirement for symmetry or antisymmetry in the wavefunctions.

Discussion Character

  • Conceptual clarification, Assumption checking, Problem interpretation

Approaches and Questions Raised

  • The original poster attempts to derive wavefunctions for various cases of particles (distinguishable bosons, identical bosons, and fermions) and expresses uncertainty about the correct forms for the bosonic cases. Participants discuss the necessity of symmetry for bosons and antisymmetry for fermions, questioning the original poster's interpretations.

Discussion Status

Some participants provide guidance on the correctness of the wavefunctions proposed by the original poster, particularly for the fermionic case. There is an acknowledgment of the need for a symmetric wavefunction for identical bosons, and clarification is offered regarding the distinction between the cases of distinguishable and identical particles. The discussion remains open as participants explore the implications of the symmetry requirements.

Contextual Notes

Participants note that the bosons in question are spinless, which influences the construction of their wavefunctions. There is also mention of the specific energy expressions and eigenfunctions relevant to the problem context.

stunner5000pt
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Homework Statement


Consider two noninteracting particles p and q each with mass m in a cubical box od size a. Assume the energy of the particles is

E = \frac{3 \hbar^2 \pi^2}{2ma^2} + \frac{6\hbar^2 pi^2}{2ma^2}

Using the eigenfunctions
\psi_{n_{x},n_{y},n_{z}} (x_{p},y_{p},z_{p})
and
\psi_{n_{x},n_{y},n_{z}} (x_{q},y_{q},z_{q})

write down the two particle wave functions which could describe the system when the particles are
a) distinguishable, spinless bosons
b) identical, spinless bosons
c) identical spin-half fermions in a symmetric spin state
d) identical spin half fermions in an antisymmetric spin state

Homework Equations


For a cube the wavefunction is given by

\psi_{n_{x},n_{y},n_{z}} = N \sin\left(\frac{n_{x}\pi x}{a}\right)\sin\left(\frac{n_{y}\pi y}{a}\right)\sin\left(\frac{n_{z}\pi z}{a}\right)

E = \frac{\hbar^2 \pi^2}{2ma^2} (n_{x}^2 + n_{y}^2 +n_{z}^2)

The Attempt at a Solution


for the fermions the wavefunction mus be antisymmetric under exhange
c) \Phi^{(A)}(p,q) = \psi^{(A)} (r_{p},r_{q}) \chi^{(S)}_{S,M_{s}}(p,q)
where chi is the spin state

so since the energy is 3 E0 for the first particle there possible value nx,ny,nz are n=(1,1,1) and the second particle n'=(1,1,2).

we could select
\Psi^{(A)} (x_{p},x_{q},t) = \frac{1}{\sqrt{2}} (\psi_{n}(x_{p})\psi_{n'}(x_{q} - \psi_{n}(x_{q})\psi_{n'}(x_{p}) \exp[-\frac{i(E_{n} + E_{n'})t}{\hbar}
A means it is unsymmetric
the spin state chi could be
\chi^{(S)}_{1,1}(p,q) = \chi_{+}(p) \chi_{-}(q)
S means it is symmetric

For d it is similar but switched around

for a) and b) i have doubts though
For a) the bosons must be distinguishable so we could have WF like this

\Psi_{1} (r_{p},r_{q},t) = \psi_{n}(r_{p})\psi_{n'}(r_{q}) \exp[-\frac{i(E_{n} + E_{n'})t}{\hbar}
for one of the particles. Under exchange this would be symmetric.

b) if the bosons are identical then we simply have to construct a wavefunction that is smmetric like we did in part c for the fermions.

Is this right? Please help!

thanks for any and all help!
 
Last edited:
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bump :biggrin:
 
by the way \chi= \chi_{S,M_{S}}

and
\chi_{+} when Ms = +1/2
and
\chi_{-} when Ms = -1/2
 
Hi stunner5000pt,

I'm just learning this stuff myself, but I'll try to help. Your answer to part c looks correct. The spatial part of the wf was chosen to be antisymmetric, since the spin state is given to be symmetric, so that the *overall* wf is antisymmetric.

stunner5000pt said:
for a) and b) i have doubts though
For a) the bosons must be distinguishable so we could have WF like this

\Psi_{1} (r_{p},r_{q},t) = \psi_{n}(r_{p})\psi_{n'}(r_{q}) \exp[-\frac{i(E_{n} + E_{n'})t}{\hbar}
for one of the particles. Under exchange this would be symmetric.

No it wouldn't be! But that's okay! :smile: Because the particles are meant to be distinguishable. So I think your answer is correct...an acceptable wavefunction for a two-particle system is the product of the individual one-particle wavefunctions, *if* you know that one is in the state n, and
the other in the state n', because you are able to tell the difference between them.

stunner5000pt said:
b) if the bosons are identical then we simply have to construct a wavefunction that is smmetric like we did in part c for the fermions.

Yes, you do have to construct a wavefunction that is symmetric. But no, it's not like part c, because in part c, you constructed a wf that was antisymmetric. :-p Not only that, but your bosons are spinless, so you'd only have a spatial part to your wavefunction, and it would have to be symmetric on its own.

Hope this helps
 

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