What does this symbol mean in a chemical equation?

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SUMMARY

The symbol "↓" in the chemical equation Ca(OH)2(aq) + Na2CO3(s) → CaCO3 ↓ + 2 NaOH(aq) indicates that calcium carbonate (CaCO3) precipitates out of the solution, confirming it is not dissolved. This is analogous to the "↑" symbol in the equation CaCO3 + 2HCl → CO2↑ + CaCl2 + H2O, which signifies the evolution of gas. The presence of states of matter (solid, liquid, gas) in chemical equations is often redundant when using these symbols, as they already imply the physical state of the reactants and products.

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thebosonbreaker
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I recently stumbled across a chemical equation, which had a symbol I have never seen before.
If anyone can tell me what this symbol means, I would be very grateful.

Here's the equation:
Ca(OH)2(aq) + Na2CO3(s) → CaCO3 ↓ + 2 NaOH(aq)

...and I'd like to know what the "↓" symbol means.

Many thanks in advance.
 
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It means that CaCO3 precipitates and is not in solution.
 
Just like ↑ in

CaCO3 + 2HCl → CO2↑ + CaCl2 + H2O

means evolving gas.

Note that is the reagent states are given (as (g), (aq), (s)) these arrows are typically redundant.
 
Ahh! That does make sense.

So that would mean that this reaction could be used to produce just NaOH if the CaCO3 was removed (which the arrow states would be possible because the CaCO3 is not chemically bonded in any way with the NaOH, and could therefore be removed.)

Thanks a lot!
 

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