What Indicators Are Best for Titration of HNO3 with NaCN and LiOH with HNO2?

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SUMMARY

The discussion focuses on selecting suitable indicators for titrations involving HNO3 with NaCN and LiOH with HNO2. For the titration of HNO3 and NaCN, the appropriate indicator should have a transition range that aligns with the pH at the equivalence point, which is typically acidic. In the case of LiOH and HNO2, the indicator must have a pH range around 8-10, as the pKa of the nitrite ion (NO2-) is 5.1E-4, indicating a basic solution at equivalence. The key steps include calculating the pH of the resulting salt solution and selecting the correct indicator based on these calculations.

PREREQUISITES
  • Understanding of acid-base titration principles
  • Knowledge of pKa and Ka values
  • Familiarity with pH indicators and their transition ranges
  • Basic chemistry knowledge regarding hydrolysis of salts
NEXT STEPS
  • Research the properties of common pH indicators suitable for weak acid-strong base titrations
  • Learn how to calculate the pH at the equivalence point for various acid-base reactions
  • Study the hydrolysis of salts and its effect on pH
  • Explore the relationship between pKa values and indicator selection in titrations
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Chemistry students, educators, and laboratory technicians involved in titration experiments and acid-base chemistry.

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Homework Statement


Select a suitable indicator for each of the following titrations:
HNO3 added to NaCN

LiOH added to HNO2

Homework Equations


all i know is Ka(HIn)=[H3O] at transition point and pKa(HIn)=pH at transition point



The Attempt at a Solution


the book I have is really skimpy on this, and is has no other information, or even an example.

For LiOH + HNO2 <----> H20 + LiNO2
ic that Li doesn't hydrolyze and NO2 does. the ka for NO2 is 5.1E-4 which should also be the Ka then I -log(5.1E-4) and I get the wrong answer? The answer should be an indicator with a pH range around 8-10. I don't get it, can someone please help me?
 
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