What is Plasmonic Photocatalysis and How Can It Help Remove Hydrogen Sulfide?

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SUMMARY

Plasmonic photocatalysis, developed by researchers at Rice University, efficiently converts hydrogen sulfide into hydrogen gas and sulfur using light energy, eliminating the need for high-temperature processes like the Claus method. This innovative approach utilizes a silicon dioxide surface embedded with gold nanoparticles to generate high-energy electrons through localized surface plasmon resonance (LSPR). The process operates at low temperatures and energy inputs while producing valuable byproducts, showcasing potential applications in CO2 conversion and other chemical reactions.

PREREQUISITES
  • Understanding of plasmonic photocatalysis and its mechanisms
  • Familiarity with localized surface plasmon resonance (LSPR)
  • Knowledge of chemical reaction pathways and catalysis
  • Basic principles of nanoparticle interactions with light
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  • Research the fundamentals of localized surface plasmon resonance (LSPR)
  • Explore the applications of plasmonic photocatalysis in CO2 reduction
  • Investigate hybrid catalysts combining plasmonic and non-plasmonic metals
  • Learn about the role of charge carriers in plasmonic catalysis
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Researchers, chemists, and environmental scientists interested in advanced catalytic processes, particularly those focused on sustainable methods for hydrogen sulfide removal and CO2 conversion.

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I listened to the following commentary: Getting Rid Of Hydrogen Sulfide
https://earthwiseradio.org/podcast/getting-rid-of-hydrogen-sulfide/

Researchers at Rice University have developed a method for turning hydrogen sulfide into hydrogen gas and sulfur in a single step. Called plasmonic photocatalysis, it not only gets rid of an undesirable substance, it does so by producing valuable byproducts.

The established way of getting rid of hydrogen sulfide is called the Claus process. It requires multiple steps, including some that require combustion chambers heated to 1,500 degrees Fahrenheit. The end product is sulfur and water.

The Rice University process gets all of its energy from light. A surface of grains of silicon dioxide is dotted with tiny gold nanoparticles. These particles interact strongly with a specific wavelength of visible light and cause plasmonic reactions that create short-lived, high-energy electrons that drive the catalysis of hydrogen sulfide.

Low temperature, low energy input, and two useful products!

Maybe there are other applications/processes.

Localized surface plasmon resonance (LSPR) allows nanoparticles (NPs) to harvest light and concentrate it near the nanoparticle surface. Light energy is utilized in the generation of excited charge carriers as well as heat. Plasmonic catalysts used these energetic charge carriers (and the heat) to drive chemical reactions on their surface and allowed the discovery of novel and selective reaction pathways that were not possible in thermal catalysis. This review discusses the fundamentals of plasmonic catalysis and its application for CO2 conversion to fuel and chemicals. We first discussed the fundamentals of LSPR and the mechanism of plasmonic photocatalysis, using the concepts of the dielectric function, charge carrier generation, and relaxation pathways. We then reviewed various charge carrier-mediated activation of molecules (their chemical bonds) on the surface of plasmonic nanocatalysts and how the extraction of charge carriers played a critical role in plasmonic catalysis. The concept of multicomponent plasmonic catalysis, a hybrid catalyst by combining plasmonic metals (Cu, Au, Ag, Al, etc.) with nonplasmonic but active catalytic metals (Pt, Pd, Ru, Rh, etc.), in close proximity to each other, was then discussed. Photocatalytic CO2 reduction reactions using the examples of each of three major pathways, (i) direct transfer of hot charge carriers to the reactant molecules, (ii) providing heat to the reactant molecules by photothermal effect, and (iii) enhancing the photon absorption rate of reactant molecules by optical near-field enhancement close to the nanocatalyst surface, were discussed.
https://pubs.acs.org/doi/10.1021/acsmaterialslett.1c00081
 
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