What is the color of chromium Cr##^{3+}##?

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Discussion Overview

The discussion centers around the color of chromium in its +3 oxidation state (Cr3+), specifically whether it is green or grey-green. Participants reference conflicting information from textbooks and explore the variability in color perception and representation in different contexts.

Discussion Character

  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • One participant seeks clarification on whether Cr3+ is green or grey-green, citing conflicting sources.
  • Another participant emphasizes the subjective nature of color perception and suggests that naming colors can be imprecise.
  • A suggestion is made to use spectrophotometers for accurate color measurement.
  • One participant notes that the color can vary based on the preparation and exposure of the sample, indicating a range from 'light green' to 'grayish green'.
  • Another participant recalls seeing Cr3+ solutions appearing green, aligning with images shared in the discussion.
  • It is mentioned that anhydrous chromium (III) chloride is purple, and that the color can depend on the ligand field as well as the metal center.
  • Some participants point out that images from different sources can lead to discrepancies in color representation, suggesting that 'green' may be a sufficient descriptor.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the exact color of Cr3+, with multiple competing views and descriptions remaining in the discussion.

Contextual Notes

The discussion highlights the limitations of color naming and perception, as well as the influence of sample preparation and environmental factors on observed color.

chwala
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kindly clarify on the color of chromium ##cr^{3+}##. Is it green or grey-green? There is a conflict in my textbook i.e Roger Norris IGCSE Chemistry and the cie syllabus content 2019. regards,
 
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No such thing as cr^{3+}, you mean Cr^{3+}.

Naming colors is never easy. First, they can be perceived differently by different people (remember the discussion about whether the dress on a picture picture was colored black and blue, or white and gold?). Second, we have names for some basic colors, but when it comes to different hues we are often at loss with naming. So actually the discussion about whether Cr3+ is green or grey-green is a bit of a moot - it is what it is, and neither name is precise enough.
 
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We do not know what color we see. Use spectrophotometers.
 
While the above answers to your question "What is the color of Chromium III ?" are correct and responsive, I can add a perspective from the chemical nature of fine art. Depending on how it is prepared and how long the sample is exposed to atmosphere expect a sample to appear 'light green' to 'grayish green' in visible light. Note the sample in post #2 may be subject to both oxidation and nitrification with resulting 'color change' as we learn in this excerpt Chemistry and compounds.
 
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Ans: Looks like both, depending for Cr2O3. See https://www.google.com/search?biw=1.....1...1..gws-wiz-img...35i39j0i67.EPzWGoCfhk4 .
242944
242945
 
I must have seen solutions of Cr+3 a couple of times and best that I remember, green; much like the color shown in post # 6, the picture on the left side.
 
Anhydrous chromium (III) chloride is purple. The color depends on the ligand field in addition to the metal center.
 

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