What Is the Physical Significance of ##\beta_{tot}## in Molecular Polarization?

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SUMMARY

The discussion centers on the physical significance of the total hyperpolarizability tensor, denoted as ##\beta_{tot}##, which is derived from the first hyperpolarizability tensor ##\beta_{ijk}##. The formula for ##\beta_{tot}## aggregates the components of the tensor, specifically combining the squares of the sums of the diagonal and off-diagonal elements. Understanding ##\beta_{tot}## is crucial for interpreting molecular polarization effects in nonlinear optics and related fields.

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This discussion is beneficial for physicists, chemists, and materials scientists interested in molecular polarization and nonlinear optical properties.

Konte
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Hi everybody,

The tensor of first hyperpolarizability ##\beta_{ijk}## is define as giving the second order or molecular polarization:
$$\mu_i^{(2)}=\sum_{jk} \, \beta_{ijk} E^j E^k$$

Now, I saw somewhere that an entity ##\beta_{tot}## can be define as:
$$\beta_{tot}=\left( (\beta_{xxx}+\beta_{xyy}+\beta_{xzz})^2+(\beta_{yyy}+\beta_{yzz}+\beta_{yxx})^2+(\beta_{zzz}+\beta_{zxx}+\beta_{zyy})^2\right)^{1/2}$$
What is the physical signification of this magnitude ##\beta_{tot}## ?

Thank you everybody.

Konte
 
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Konte said:
I saw somewhere

Where? Please give a specific reference.
 

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