Undergrad What is the physical significance of <x'|x> in quantum mechanics?

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The discussion focuses on the physical significance of the inner product <x'|x> in quantum mechanics, which is identified as the inner product of two unnormalized position states, yielding the value δ(x' - x). It is noted that this inner product does not naturally represent transition amplitudes, unlike those derived from scattering theory. The propagator <x'|e^(-iHt/ħ)|x> is emphasized as having a clear physical interpretation, representing the probability amplitude for a particle's movement over time. The conversation also highlights that while <x'|x> can be viewed as a special case of the propagator at t=0, it lacks a meaningful physical context when interpreted as a transition amplitude. Overall, the participants stress the importance of understanding the mathematical framework and context to derive physical meaning in quantum mechanics.
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What is <x'|x> in quantum mechanics? I've seen it, but I don't know what it's suppose to mean in physical terms. It this the amplitude for an unspecified particle to go from x to x' ?
 
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It is the inner product of two unnormalized position states, and has the value ##\delta(x'-x)##. It is moot to try to interpret it in terms of transitions.

Note that not every inner product has such an interpretation. only those arising from scattering theory (or its simplified toy versions) can sensibly be interpreted as transition amplitudes.
 
A. Neumaier said:
It is the inner product of two unnormalized position states, and has the value ##\delta(x'-x)##. It is moot to try to interpret it in terms of transitions..

How does it compare to <x'|e-iHt|x> ? I think this does have a physical interpretation, right?
 
friend said:
How does it compare to <x'|e-iHt|x> ? I think this does have a physical interpretation, right?
One can force an interpretation upon it, but I don't know a natural setting where this would appear as a transition amplitude.
The good transition amplitudes are ##\langle p|S|p'\rangle##, where ##p## and ##p'## are momentum or spin states and ##S## is the S-matrix (a complicated limit with a physical meaning), and in some approximations, you can replace ##S## by an interaction potential.
 
The Wikipedia article says that <x'|e-iHt/ħ|x> is the propagator that "gives the probability amplitude for a particle to travel from one place to another in a given time...", where e-iH(t'-t)/ħ is a "unitary time-evolution operator for the system taking states at time t to states at time t′ ", . OK, so it is a probability amplitude. Why is that not so obvious?

would <x'|x> simply be a propagator as above with H=0 ? Does that have any physical meaning? For example, could that be a propagator for a virtual particle, that does not have any permanent energy?
 
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friend said:
OK, so it is a probability amplitude.
This is consistent with my statement
A. Neumaier said:
One can force an interpretation upon it, but I don't know a natural setting where this would appear as a transition amplitude.
You can give it a name, and that's it. Some people like to play with names, just because it makes formulas appear less abstract.

But the propagators that are actually used in quantum mechanics are all between momentum states, not between position states. Because momentum states can be prepared (beams) while position states cannot. One doesn't observe particles jumping from one place to another.

So you can choose from the literature what you like to use. The truth is in the formulas, not in the way people think or talk about them. The latter is often highly subjective.
 
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A. Neumaier said:
But the propagators that are actually used in quantum mechanics are all between momentum states, not between position states. Because momentum states can be prepared (beams) while position states cannot.
Thanks, that makes a lot of sense.

So would <x'|x> simply be a propagator as above with H=0 ? Does that have any physical meaning? For example, could that be a propagator for a virtual particle, that exists at each position in space but does not have any permanent energy?
 
friend said:
So would <x'|x> simply be a propagator as above with H=0 ? Does that have any physical meaning? For example, could that be a propagator for a virtual particle, that exists at each position in space but does not have any permanent energy?
It's much simpler than that.

If you're going to think of ##\langle{x}'|x\rangle## as a special case of ##\langle{x}'|e^{-iHt/\hbar}|x\rangle##, it's the ##t=0## case, not the ##H=0## case. ##|x\rangle## is the position eigenstate with eigenvalue ##x##, and if that's the state of the particle at time ##t=0## then ##e^{iHt/\hbar}|x\rangle## will be its state at all times ##t\ge{0}##. In general that state will be a superposition of eigenstates, and ##\langle{x}'|e^{-iHt/\hbar}|x\rangle## picks out the amplitude of the ##|x'\rangle## components in that superposition. Not surprising, it is equal to ##\delta(x'-x)## at ##t=0## when the state is ##|x\rangle## with no other position eigenstates contributing.
 
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A. Neumaier said:
But the propagators that are actually used in quantum mechanics are all between momentum states
In addition, the transition amplitude interpretation of a propagator is still ill-conceived. The absolute square of a probability amplitude is a probability, a number between 0 and 1, while the absolute square of a propagator value can be any number, including infinity, and hence cannot have a probability interpretation.

It is highly misleading to try to interpret every inner product as an amplitude
! The physical meaning of a formula is determined by the way it is used in an argument leading to physical results, and not by making up stories about the symbols and associated virtual objects! So if you want to understand the physical meaning of a formula you need to study the context of it until you see its connection with something of true physical relevance!
 
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  • #10
Just a minute, I often see the path integral derived using this inner product by inserting the identity many time...

<x'|e-iHt/ħ|x> = ∫∫∫⋅⋅⋅∫<x'|e-iHε/ħ|x1><x1|e-iHε/ħ|x2><x2|e-iHε/ħ|x3>⋅⋅⋅<xn|e-iHε/ħ|x> dx1dx2dx3⋅⋅⋅dxn

where the integration over x1, x2, x3... xn is from - to + infinity, and ε approaches 0. So basically we have <x1|e-iHε/ħ|x2> ≈ <x1|x2>. What then are these <x1|e-iHε/ħ|x2> ≈ <x1|x2>? They don't seem to be measurable, but they do seem to be micro-wave-functions for presumably micro excursions of a particle that contribute to the total wave-function. Are these virtual particles?
 
  • #11
friend said:
Are these virtual particles?
No. The integrals are sums over histories (in QM literally, in QFT in a vague sense, as everything diverges). It is at the origin of the intuition that a quantum particle travels all possible paths. But one shouldn't take this intuition too seriously - it is just a feeble attempt to make the path integral less abstract than it is, and becomes nonsense if taken too real.
 
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  • #12
An alternative interpretation of the path integral might be that real particles traveling through space do so by transferring energy from one stationary "virtual particle", <x1|e-iHε/ħ|x2>, to the next. Otherwise, I think we are ignoring quantum fluctuations' effect on traveling particles. I know some people have real difficulty thinking in terms of virtual particles. But I think that's because there's not enough effort put into identifying where in the math they are. I've made an attempt here that seems reasonable to me. In order to say that these are not virtual particles, one would have to show the math for true virtual particles. That doesn't seem to be readily available. But I think an attempt should be made because it would offer us a way to mathematically visualize exactly what's going on in the quantum world. I think it would explain where the wave-function comes from and, thus, exactly how entanglement works. And now I'm seriously beginning to think (I need a little more time on this) that such a virtual description of the math will allow us to unite spacetime, matter, and energy.
 
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  • #13
Nugatory said:
It's much simpler than that.

If you're going to think of ##\langle{x}'|x\rangle## as a special case of ##\langle{x}'|e^{-iHt/\hbar}|x\rangle##, it's the ##t=0## case, not the ##H=0## case. ##|x\rangle## is the position eigenstate with eigenvalue ##x##, and if that's the state of the particle at time ##t=0## then ##e^{iHt/\hbar}|x\rangle## will be its state at all times ##t\ge{0}##. In general that state will be a superposition of eigenstates, and ##\langle{x}'|e^{-iHt/\hbar}|x\rangle## picks out the amplitude of the ##|x'\rangle## components in that superposition. Not surprising, it is equal to ##\delta(x'-x)## at ##t=0## when the state is ##|x\rangle## with no other position eigenstates contributing.
It must be stressed that you cannot prepare a particle in a state represented by ##|x \rangle##, because it's not a Hilbert-space vector. It belongs to a larger space, namely the dual of the dense subspace of Hilbert space, where the position operator is defined (i.e., the domain of the position operator).

Further, of course
##U(t;x,x')=\langle x|\exp(-\mathrm{i} \hat{H} t) x' \rangle,##
thus is a distribution. It only has a meaning when applied to a true state. As already stated above in this thread, it's the propagator in the position representation, i.e., if you have a system that is at ##t=0## prepared in a true pure quantum state, represented by a normalized Hilbert-space vector ##|\psi_0 \rangle##, then in the position representation you have the wave function
##\psi_0(x)=\langle x|\psi \rangle,##
which is a square-integrable function with norm 1. Then at any later time ##t## the state of the system is represented by the wave function
$$\psi(t,x)=\int_{\mathbb{R}} \mathrm{d} x' U(t;x,x') \psi_0(x)=\langle x|\exp(-\mathrm{i} \hat{H}) \psi_0 \rangle.$$
 
  • #14
Does ##\exp(-\mathrm{i} \hat{H} t/ħ) ## identify which particle the ##|\ x \rangle## refers to? I think ## \hat{H} ## specify the charge of the particle referred to by ##|\ x \rangle##. But does ## \hat{H} ## specify the spin statistics of ##|\ x \rangle## ?
 
  • #15
friend said:
Does ##\exp(-\mathrm{i} \hat{H} t/ħ) ## identify which particle the ##|\ x \rangle## refers to? I think ## \hat{H} ## specify the charge of the particle referred to by ##|\ x \rangle##. But does ## \hat{H} ## specify the spin statistics of ##|\ x \rangle## ?
This notation only makes sense when the whole system consists of a single, spinless particle. H is the energy, nt the charge.
 
  • #16
A. Neumaier said:
This notation only makes sense when the whole system consists of a single, spinless particle. H is the energy, nt the charge.
Right. We would need something like |x1, x2> in order to starting talking about whether it is symmetric or antisymmetric under a permutation of the subscripts. As I recall, this is related to is spin statistics. (It's been a while since I looked at this). So is the way |x1, x2> behaves in permutation something we assume? Or can that be derived by some operator such as the Hamiltonian. I'm reminded that the Hamiltonian has things in it like a mass term, and it determines whether there is a repulsive or attractive force between similar particles we might label as |x1> and | x2>.

The reason I ask is because the |x1> notation is not specific to what kind of particle, fermion or boson, the particle might be. So I'm wondering where that specification comes in, whether we have to assume it to even write the Lagrangian or does it come in with the introduction of coupling constants.
 
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  • #17
friend said:
(It's been a while since I looked at this).
I think you'd first read a bit more and improve in this way your formal understanding, rather than using this forum to have pointed out your (many) shortcomings in your present understanding. It is a better use of your time, and of eveyone elses, too.
 
  • #18
A. Neumaier said:
I think you'd first read a bit more and improve in this way your formal understanding, rather than using this forum to have pointed out your (many) shortcomings in your present understanding. It is a better use of your time, and of eveyone elses, too.
Your comments only support the fact that I must be asking questions that do not have quick and easy answers. Otherwise, you'd simply answer them since you are so informed on the situation. I don't have a lot of time to go through many texts looking for connections that they don't focus on. If someone can help me with what exact words, theorems, equations, and concepts that I seem to be trying to find, then I can get into the books and do my own research. Or are you suggesting that this forum is the place where only experts in the field go to find answers? If I already knew it all, I wouldn't be here.
 
  • #19
friend said:
Or are you suggesting that this forum is the place where only experts in the field go to find answers? If I already knew it all, I wouldn't be here.
No, but you should not expect to get useful answers without accompanying self-study. Quantum mechanics cannot be learned through bed-time reading and superficial discussions on the web.

Each answer given to you should trigger enough motivation to read something more systematic. Otherwise you'll end up with half-baked pseudo truths that don't make sense to anyone.
 
  • #20
Thank you. I still await some further insights.
 
  • #21
I've given an answer. If you don't understand it, please take a good textbook and study it. We cannot rewrite textbooks in form of forum postings! A good one is Sakurai, Modern Quantum Mechanics.
 
  • #22
friend said:
I still await some further insights.
You'll get it if you do some serious study based on what was discussed in this thread, not by asking further questions. Most insights do not come for free but only when you are sufficiently prepared.
 
  • #23
So I remembered that this was addressed in a book I once read, https://www.amazon.com/dp/1441982663/?tag=pfamazon01-20. On page 194, the author summarizes how a "spinor" describes spin-1/2 particles, fermions. And the author says that the SU(2) symmetry of the Standard Model is the generator of spinor rotations. So it seems that fermions/bosons come from the symmetries of the Lagrangian of the Standard Model. And the Lagrangian can be rewritten as the Hamiltonian. So it seems, yes, the spin of a particle does come from H.
 
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  • #24
friend said:
fermions/bosons come from the symmetries of the Lagrangian of the Standard Model.
No; they are an input to the standard model. You better do some thorough reading instead of posting poorly remembered and poorly assembled fragments of facts.

Also what you write has nothing to do with your original question, and hence doesn't belong into this thread. (And next time post with the rating B, not I, since what you are lacking are very basic things.)
 
  • #25
A. Neumaier said:
No; they are an input to the standard model. You better do some thorough reading instead of posting poorly remembered and poorly assembled fragments of facts.
As opposed to what, giving you my word alone for it.

A. Neumaier said:
Also what you write has nothing to do with your original question, and hence doesn't belong into this thread.
I asked what is <x'|x> which seems to be for an unspecified generic particle. I wanted to know where the specificity comes from. And it seems that information (including charge and spin) comes from the Lagrangian.

And once again you've reduced the thread to condescension. I think this thread is over.
 
  • #26
What is |<x'|x>|2 = <x'|x><x'|x>* = <x'|x><x|x'> ? Is this a legitimate probability, or probability density?
 
  • #27
No, it's obviously not. Again, generalized eigenstates of self-adjoint operators in the continuous part of their spectrum are never proper Hilbert-space vectors and thus do not represent (pure) quantum states. They are distributions and belong to the dual space of the domain of the self-adjoint operator. You must not multiply them. In your case of a position eigenvector you have
$$\langle x'|x \rangle=\delta(x'-x).$$
This clearly shows you that you must not take its square!

For an introduction to the modern treatment of these issues in terms of the "rigged-Hilbert space formalism" see Ballentine, Quantum Mechanics, Addison-Wesley. More mathematical details can be found in

A. Galindo and P. Pascual. Quantum Mechanics. Springer Verlag, Heidelberg, 1990. 2 Vols.
 
  • #28
As I mentioned in post #5 in this thread, <x'|e-iHt/ħ|x> is a propagator which is a probability amplitude per this wikipedia.org article, where e-iHt/ħ is the unitary operator U(t,t') of that article. And Nugatory in post #8 pointed out that <x'|x> is <x'|e-iHt/ħ|x> as t→0.

My question is, at what value of t as it approached 0 does <x'|e-iHt/ħ|x> stop being a probability amplitude such that it cannot be treated as any other probability amplitude so that we can take its modulus squared to get a probability?
 
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  • #29
friend said:
a propagator which is a probability amplitude per this wikipedia.org article
Don't trust everything written in wikipedia! The entries in wikipedia are written by fallible people, usually not even by experts. Therefore not everything wikipedia says is true. Here it is completely mistaken. See post #9.
 
  • #30
A. Neumaier said:
...while the absolute square of a propagator value can be any number, including infinity, and hence cannot have a probability interpretation.
Are we missing a normalization factor in order to turn a propagator into a probability amplitude?
 

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