What is the ratio of energies in a hydrogen atom and how can it be calculated?

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SUMMARY

The discussion focuses on calculating the ratio of kinetic energy to potential energy for an electron in a hydrogen atom, specifically in its ground state. Participants emphasize using the kinetic energy operator from the Hamiltonian and the Coulomb potential to derive the necessary values. The most probable electron orbit radius is determined using the wave function's probability density. The energy levels of hydrogen are inversely proportional to the square of the principal quantum number, n.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly the hydrogen atom model.
  • Familiarity with Hamiltonian mechanics and kinetic energy operators.
  • Knowledge of Coulomb's law and its application in atomic physics.
  • Ability to work with wave functions and probability densities in quantum mechanics.
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  • Learn how to derive the energy levels of hydrogenic atoms using quantum mechanics.
  • Study the application of the kinetic energy operator in quantum systems.
  • Explore the concept of expectation values and their significance in quantum mechanics.
  • Investigate the relationship between the Bohr radius and potential energy in hydrogen atoms.
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Students and professionals in physics, particularly those specializing in quantum mechanics, atomic physics, and anyone interested in the energy dynamics of hydrogen atoms.

Erwin Kreyszig
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[SOLVED] Energies of a Hydrogen Atom

1. I have a question on the ratio of energies of an electron in a hydrogen atom. It seems quite simple, but yet seem to be struggling...can anyone help?
2. The question is: "calculate the most probable value of the electron-orbit radius, r, and the ratio of the electron kinetic energy to its potential energy in the ground state of the hydrogen atom"
3. So far i have found the most probable value of the electrons orbit radius, by taking the |\Psi|^2 and multiplying it by the volume element, all in spherical polars. What i am struggling on is the ratio of the energies.

Thanks EK
 
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For the kinetic Energies just take the kinetic part of the hamiltonian as a kinetic energy operator ?
 
Q1:
It depends on what level you should do this problem.

The general formula for hydrogenic atom energy levels are very simple and you should know that one by heart. Or should you be able to derive it?

The energy levels are proportional to n^{-2}, does this look familiar?
 
Thanks guys, so as it is in the ground state this solution is even easier, it is just taking the K.E operator and putting it over the potential (the attractive force on the electron) Thanks for all your help

EK
 
Mr.Brown said:
For the kinetic Energies just take the kinetic part of the hamiltonian as a kinetic energy operator ?


So i can use the K.E from the Hamiltonian, and use the potential as the coulomb interaction between the electron and the proton, then equate the ratio from those?

Thanks EK
 
Yeah just calculate the kinetic energy with the KE operator.
Then calculate the mean radius of that given wave function put that in coulombs formula and equate the ratio :)
 
Mr.Brown said:
Yeah just calculate the kinetic energy with the KE operator.
Then calculate the mean radius of that given wave function put that in coulombs formula and equate the ratio :)

Perfect, thanks for all your help.

EK
 
Mr.Brown said:
Yeah just calculate the kinetic energy with the KE operator.
Then calculate the mean radius of that given wave function put that in coulombs formula and equate the ratio :)

I am obviously being dumb here, but how can i calculate the kinetic energy using the KE operator? What is it operating on? Do i chose a probable wave function, i.e. guess at it being and exponential, for example, e^-cr, and operate on that?

Thanks

EK
 
Mr.Brown said:
Yeah just calculate the kinetic energy with the KE operator.
Then calculate the mean radius of that given wave function put that in coulombs formula and equate the ratio :)

Sorry to be retarded, but to find the potential then you have to find the expectation value of the ground state radius, which is the Bohr radius yes? Then you sub that Bohr radius into the coulombs law and that is your Potential?
Then equate then with that i can find my ratio of the two energies?


EK
 

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