What is the ratio of energies in a hydrogen atom and how can it be calculated?

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Homework Help Overview

The discussion revolves around calculating the ratio of kinetic energy to potential energy for an electron in a hydrogen atom, specifically in its ground state. The original poster seeks assistance in understanding the methodology for determining this ratio and the most probable electron orbit radius.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss using the kinetic energy operator from the Hamiltonian and the potential energy related to the Coulomb interaction. There are questions about deriving energy levels and the appropriate wave functions to use for calculations.

Discussion Status

The conversation includes various attempts to clarify the calculation process, with some participants suggesting specific methods for determining kinetic and potential energies. There is an ongoing exploration of how to apply the Hamiltonian and the implications of the ground state conditions, but no consensus has been reached on a definitive approach.

Contextual Notes

Participants are navigating the complexities of quantum mechanics and the specific requirements of the homework problem, including the need to derive certain values and the potential assumptions involved in the calculations.

Erwin Kreyszig
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[SOLVED] Energies of a Hydrogen Atom

1. I have a question on the ratio of energies of an electron in a hydrogen atom. It seems quite simple, but yet seem to be struggling...can anyone help?
2. The question is: "calculate the most probable value of the electron-orbit radius, r, and the ratio of the electron kinetic energy to its potential energy in the ground state of the hydrogen atom"
3. So far i have found the most probable value of the electrons orbit radius, by taking the |\Psi|^2 and multiplying it by the volume element, all in spherical polars. What i am struggling on is the ratio of the energies.

Thanks EK
 
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For the kinetic Energies just take the kinetic part of the hamiltonian as a kinetic energy operator ?
 
Q1:
It depends on what level you should do this problem.

The general formula for hydrogenic atom energy levels are very simple and you should know that one by heart. Or should you be able to derive it?

The energy levels are proportional to n^{-2}, does this look familiar?
 
Thanks guys, so as it is in the ground state this solution is even easier, it is just taking the K.E operator and putting it over the potential (the attractive force on the electron) Thanks for all your help

EK
 
Mr.Brown said:
For the kinetic Energies just take the kinetic part of the hamiltonian as a kinetic energy operator ?


So i can use the K.E from the Hamiltonian, and use the potential as the coulomb interaction between the electron and the proton, then equate the ratio from those?

Thanks EK
 
Yeah just calculate the kinetic energy with the KE operator.
Then calculate the mean radius of that given wave function put that in coulombs formula and equate the ratio :)
 
Mr.Brown said:
Yeah just calculate the kinetic energy with the KE operator.
Then calculate the mean radius of that given wave function put that in coulombs formula and equate the ratio :)

Perfect, thanks for all your help.

EK
 
Mr.Brown said:
Yeah just calculate the kinetic energy with the KE operator.
Then calculate the mean radius of that given wave function put that in coulombs formula and equate the ratio :)

I am obviously being dumb here, but how can i calculate the kinetic energy using the KE operator? What is it operating on? Do i chose a probable wave function, i.e. guess at it being and exponential, for example, e^-cr, and operate on that?

Thanks

EK
 
Mr.Brown said:
Yeah just calculate the kinetic energy with the KE operator.
Then calculate the mean radius of that given wave function put that in coulombs formula and equate the ratio :)

Sorry to be retarded, but to find the potential then you have to find the expectation value of the ground state radius, which is the Bohr radius yes? Then you sub that Bohr radius into the coulombs law and that is your Potential?
Then equate then with that i can find my ratio of the two energies?


EK
 

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