Start by considering the 1-dimensional case: measure in ##\mathbb{R}^1## is a generalization of length. For an interval of the form ##[a,b]##, the length is simply ##b-a##, and we define the measure of this interval to also be ##b-a##. For a more general set ##A \subset \mathbb{R}##, it's clearly possible to cover ##A## with countably many intervals of the form ##[a,b]##, and if we add up the lengths of these intervals, then surely the "length" of ##A## can't be greater than that sum. So, we can reasonably define the "length" of ##A## to be the infimum taken over all possible ways of covering ##A## with a countable union of intervals.
Now consider some concrete examples. If ##A = \{a\}## is a set containing one point, then we may also write it as the zero-length interval ##[a,a]##, so we expect its measure to be ##a-a = 0##. In terms of the infimum definition, we can see that any interval of the form ##[a-\epsilon, a+\epsilon]## (where ##\epsilon > 0##) will cover ##A##. The length of the interval ##[a-\epsilon, a+\epsilon]## is ##2\epsilon##, so the measure of ##A## is at most ##2\epsilon##. This is true for any ##\epsilon > 0##, so that forces ##m(A) = 0##, as expected.
We can make a similar argument to show that a set containing a finite number of points also has measure zero.
Similarly, a set containing a countably infinite number of points also has measure zero. Sketch of proof: let ##(x_n)## be an enumeration of the elements of ##A##. Let ##\epsilon > 0##. Then we may cover each point ##x_n## with an interval of length ##\epsilon / 2^n##, and the sum of the lengths of these intervals is ##\sum \epsilon / 2^n = \epsilon##. Thus the measure of ##A## is at most ##\epsilon##. But ##\epsilon## was arbitrary, so ##m(A) = 0##.
We can even find sets with uncountably many elements, but which still have measure zero. The classic example is the Cantor set.