What the heck is meant by Pauli force/effect ?

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Discussion Overview

The discussion revolves around the concept of the "Pauli force" or "Pauli effect" as it relates to the Pauli exclusion principle in the context of solid state physics. Participants explore whether there is an actual repulsive force acting on fermions due to their exclusion principle or if this is a misinterpretation by educators.

Discussion Character

  • Debate/contested
  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • One participant questions the existence of a "Pauli force," arguing that the Pauli exclusion principle only states that two fermions cannot occupy the same state and does not imply a repulsive force.
  • Another participant suggests that the Pauli exclusion principle can be interpreted as an effective force in certain approximations, such as the Hartree-Fock approximation, where it contributes to the Hamiltonian as "exchange energy," which can be either attractive or repulsive.
  • There is a mention of common errors in interpreting the Pauli exclusion principle in solid state physics, specifically referencing a textbook that uses it to justify the Lennard-Jones potential's repulsive term.
  • A request for sources that clarify the relationship between the Pauli exclusion principle and effective forces, particularly in relation to the Hartree-Fock approximation, is made by participants.
  • Another participant refers to previous discussions on the forum that addressed similar questions, indicating that the standard explanations may not fully resolve the issue for everyone.

Areas of Agreement / Disagreement

Participants express differing views on the interpretation of the Pauli exclusion principle and its implications regarding repulsive forces. There is no consensus on whether the concept of a "Pauli force" is valid or if it is a misinterpretation.

Contextual Notes

Participants note that the effective potential arising from the Pauli exclusion principle can vary in sign depending on the specific interactions and approximations used, indicating that the discussion is nuanced and context-dependent.

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What the heck is meant by "Pauli force/effect"?

I'm a last year physics undergrad and whenever I have a physics class given by an experimental physicist (e.g. solid state physics), they sometimes say things like "... and because of the Pauli force these two electrons are repelled ..." and whenever I enquire about what is meant, I get an answer like "it's due to the Pauli exclusion principle".

But the latter only states that two fermions cannot be in exactly the same state; it says nothing about a repulsive force that acts on two fermions close to each other. In essence the Pauli exclusion principle does nothing to prevent two fermions in being arbitrarily similar states, as long as the states are not exactly the same.

So what is the deal: is there an actual Pauli force additional to the Pauli exclusion principle (NB: let's not get into a semantic discussion about the word "force", call it what you will, I'm simply referring to the so-called repulsive effect of two fermions close to each other)? Or are my experimental physicis professors botching the concept of Pauli exclusion principle, making their arguments using it fallacious (i.e. there is only the Pauli exclusion principle, no repulsive effect)?
 
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mr. vodka said:
I'm a last year physics undergrad and whenever I have a physics class given by an experimental physicist (e.g. solid state physics), they sometimes say things like "... and because of the Pauli force these two electrons are repelled ..." and whenever I enquire about what is meant, I get an answer like "it's due to the Pauli exclusion principle".

But the latter only states that two fermions cannot be in exactly the same state; it says nothing about a repulsive force that acts on two fermions close to each other. In essence the Pauli exclusion principle does nothing to prevent two fermions in being arbitrarily similar states, as long as the states are not exactly the same.

So what is the deal: is there an actual Pauli force additional to the Pauli exclusion principle (NB: let's not get into a semantic discussion about the word "force", call it what you will, I'm simply referring to the so-called repulsive effect of two fermions close to each other)? Or are my experimental physicis professors botching the concept of Pauli exclusion principle, making their arguments using it fallacious (i.e. there is only the Pauli exclusion principle, no repulsive effect)?

You're perfectly right, your professor used the Pauli exclusion principle in a wrong way.
I think it's common in solid state physics to do the same error, I've read the same thing in the Ashcroft and Mermin book to justify the Lennard-Jones potential repulsive term.

Pauli principle states that the state of a system of fermions is anti-symmetric in the excange of two fermions.
It can be interpret with a effective force when, for example, you use the Hartree-Fock approximation. In doing this you find that the anti-symmetry of the wave function acts as an additiona term in the Hamiltonian, the "excange energy". This energy is though not necessarily positive, for example in the "jellium" model you find its effect is actractive. The specific form of this energy depends on both the interaction and the wavefunction you're using as an approximation.

In conclusion it's right to think about the Pauli principle as an effective energy in some approximation, but you can't know a priori if it's an actractive or a repulsive contribution.

Ilm
 
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I see, interesting... Do you know of a source that addresses this issue, i.e. that mentions the common fallacious reformulations and in what ways it is correct (apparently related to the Hartree-Fock approximation)?
 


mr. vodka said:
I see, interesting... Do you know of a source that addresses this issue, i.e. that mentions the common fallacious reformulations and in what ways it is correct (apparently related to the Hartree-Fock approximation)?
I don't know where to find a general treatment of this issue.

You can simply try to find something on the excange energy and then constate it can be both positive or negative, maybe checking this explicitly in different examples.

For a simple treatment of Hartree-Fock approximation you can read almost every solid state physics book (check it on physics forum), even Ashcroft, Mermin, Solid State Physics (I personally hated this book :mad:).
You can certainly find some example here where anti-symmetry of the state produce a positive term in the energy of the system.
Only believe in what is demonstrated though :smile:

For a rigorous treatment (but not so easy) of Hartree-Fock approximation look for books on many-body quantum physics like Fetter, Walecka, Quantum Theory of Many-Particle Systems.
Here you can find even the very simple example of the jellium model (not using Hartree-Fock if I remember it right), where anti-symmetry of the state produce a negative term in the mean energy of the system.

edit: to avoid misunderstanding, to my knowledge treating anti-symmetry of fermions states as an effective potential is not strictly related to Hartree-Fock, which is only one of the possible approximations resulting in such a term in the Hamiltonian.

Ilm
 
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This question has in fact been asked a couple of times before on PF, for example by myself a year or two ago, see here:

https://www.physicsforums.com/showthread.php?t=409034

The discussion gets a bit off-topic after a while, but you should at least read through the first pages.

It is clear from that discussion what the standard explanation for this issue is, but I'm not so sure that it explains it fully for me (yet, maybe it's only a matter of thinking it through/working through math).
 

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