Where Does the Second Chlorine Radical Go in Methane Chlorination?

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SUMMARY

The discussion focuses on the chlorination of methane, specifically the fate of the second chlorine radical produced during the initiation step. The initiation step generates two chlorine radicals from Cl2, with one radical reacting with a methyl group to form a methyl radical and HCl. The second chlorine radical remains unaccounted for in the propagation steps, as it can react with additional methane molecules or participate in termination reactions, ultimately forming Cl2 by bonding with another radical. This clarification is essential for understanding the complete mechanism of methane chlorination.

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Homework Statement



The initiation step in chlorination of methane is as follows...

http://upload.wikimedia.org/wikipedia/en/thumb/3/32/MethaneChlorinationMechanismInitiation.svg/260px-MethaneChlorinationMechanismInitiation.svg.png

We get two chlorine radicals as a result.

Next we have two propagation steps

http://upload.wikimedia.org/wikipedia/en/4/48/MethaneChlorinationPropagationStep.svg (won't let me embed the pic, sorry guys!)Ok, my understanding of this is... in the initiation step, the Cl2 was broken into two Cl radicals. ONE Cl radical moved on to the next step and reacted with the methyl group forming a methyl radical and HCl. THEN, the methyl radical reacted with Cl2 to form chloromethane and a chlorine radical.

My question is, Where does the SECOND Cl radical that was produced in the initiation step go? Because only ONE Cl radical reacted with the methyl group and then the methyl radical reacted with Cl2. In my mind, there is a Cl radical unaccounted for, but this is not explained in any example I can find (in a book or online)?

Thanks!
 
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It performs the same reaction with other molecules of methane. Eventually, you can get termination reactions that get rid of the radicals (often, this involves two radicals bonding together, e.g. Cl• + Cl• --> Cl2).
 

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