Why Distance Between Lines of Hydrogen Spectrum Decreases

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    Hydrogen Spectrum
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Discussion Overview

The discussion centers around the apparent contradiction between the increasing distances between energy shells in the hydrogen atom and the decreasing distances between lines in the hydrogen spectrum. Participants seek to understand the relationship between these two phenomena, referencing visual aids to clarify their points.

Discussion Character

  • Conceptual clarification, Debate/contested

Main Points Raised

  • One participant notes that the formula for the radius of the hydrogen atom indicates that the distance between shells increases with higher principal quantum numbers.
  • Another participant requests a careful explanation of the trend in the hydrogen spectrum, referencing a specific image.
  • A third participant points out potential labeling errors in the referenced image, suggesting that the labels may not accurately represent the hydrogen spectrum.
  • One participant urges the original poster to clarify their question in relation to the figure they are using.

Areas of Agreement / Disagreement

Participants express uncertainty regarding the accuracy of the figure and its labels, indicating a lack of consensus on how to interpret the data presented. The discussion remains unresolved as to why the distances between spectral lines decrease.

Contextual Notes

Participants have not fully established the assumptions or definitions related to the spectral lines and energy levels, which may affect their interpretations.

Ali Asadullah
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Why distances between lines of hydrogen spectrum decreases even though the distance between the shells of Hydrogen increases as we go to higher shells?

r=Ɛn2h2/πme

where
m=mass of electron,
e=charge on electron
h=planck's constant
n=principle quantum number
r=radius of hydrogen atom

This formula shows that the distance between the shells increases with the increase in Principle Quantum number.
Then why the distances between lines of hydrogen spectrum decreases?
 
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Ali Asadullah said:
Why distances between lines of hydrogen spectrum decreases even though the distance between the shells of Hydrogen increases as we go to higher shells?
Here's a picture showing the hydrogen spectrum:

http://web.stteresa.edu.hk/~kfyuen/s6spectrum2.jpg

Can you carefully explain the trend again using the picture as reference?
 
Last edited by a moderator:
Gokul43201 said:
Here's a picture showing the hydrogen spectrum:

http://web.stteresa.edu.hk/~kfyuen/s6spectrum2.jpg

Can you carefully explain the trend again using the picture as reference?

Whoops .. I think those labels are wrong! The H-atom spectra is the line spectrum on the bottom.

:wink:
 
Last edited by a moderator:
Yes, there's definitely something wrong with that figure!

Back to the OP - please post a link to the figure you are using and rewrite your question specifically in the context of the figure.
 

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