The main difference is that in dc the electrons flow in one direction, like water through pipes. In AC the electrons keep moving back and forth.
AC can take advantage of things like transformers, since they need a CHANGING magnetic field to work (and with AC the magnetic field oscillates with the back-forth motion of the electrons).
A transformer allows you to trade current for voltage, and vice-versa. Since in power lines the higher the current, the less efficient they are, raising the voltage to stupidly high levels while lowering the current to stupidly low levels can increase their efficiency, letting you send power further away without losing it all by the time it gets there.