You mean, why can't a (free) electron just suddenly spit out a photon giving a process: [itex]e\rightarrow e\gamma[/itex]? Or why can't a (free) electron just suddenly absorb a (free) photon to become a new electron: [itex]e\gamma\rightarrow e[/itex]? Or why can't a (free) photon suddenly turn into a (free) electron-positron pair: [itex]\gamma\rightarrow e^+e^-[/itex]?
Choose any of these processes. Now write down the conservation law for energy and momentum (so there are 4 equations in all). Also write down the on-shell conditions for the electron ([itex]E_e^2-\vec{p}_e\cdot\vec{p}_e=m_e^2[/itex]) and the photon ([itex]E_\gamma^2-\vec{p}_\gamma\cdot\vec{p}_\gamma=0[/itex]), where I have set c=1 for simplicity. Using these equations, solve for [itex]E_e,\vec{p}_e,E_\gamma,\vec{p}_\gamma[/itex].
Can't do it, can you?!