Why does the kinetic operator depend on a second derivative?

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Discussion Overview

The discussion centers around the dependence of the kinetic energy operator on the second spatial derivative of a wavefunction, as expressed in the formula T = -(ħ/2m)∇². Participants explore the origins of this relationship, comparing it to classical mechanics and the expression for kinetic energy.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • Steven questions the origin of the dependence of the kinetic energy operator on the second spatial derivative and seeks a connection to classical mechanics.
  • Some participants suggest that the expression for T may contain a typo, proposing that it should be hbar² instead of ħ.
  • One participant explains that the kinetic energy operator can be derived from the operator form of momentum, leading to T = (-ħ²/2m)∇².
  • Another participant agrees with the derivation and emphasizes that the kinetic energy of a classical wave would also be proportional to ∇².
  • However, a later reply contests this by stating that macroscopic, nonrelativistic kinetic energy is always given by (1/2)mv², implying a distinction between classical and quantum descriptions.
  • Bill introduces the idea that the answer to the dependence of T on the second derivative is related to symmetry, referencing a source for further reading.
  • One participant encourages another to learn LaTeX, suggesting a growing engagement in the discussion.

Areas of Agreement / Disagreement

There is no consensus on the interpretation of the kinetic energy operator's dependence on the second derivative. Multiple competing views remain, particularly regarding the relationship between classical and quantum mechanics and the correctness of the expression for T.

Contextual Notes

Participants express uncertainty about the correct form of the kinetic energy operator and its derivation, indicating potential limitations in their understanding or assumptions about classical versus quantum mechanics.

Steven Hanna
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The formula T = -(ħ/2m)∇2 implies that T is proportional to the second spatial derivative of a wavefunction. What is the origin of this dependence?

In classical mechanics, T = p2/2m. Is it also the case in classical mechanics that p2/2m is proportional to a second spatial derivative? I have not been able to relate (d/dt)2 to d2/dx2 using classical mechanics.
Thanks,
Steven
 
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Steven Hanna said:
The formula T = -(ħ/2m)∇2 implies that T is proportional to the second spatial derivative of a wavefunction. What is the origin of this dependence?

check the expression for T -i think it should be hbar^2 may be a typo.
as we know the kinetic energy operator in coordinate representation is the above expression as differential operator.
it can be derived from the operator form of momentum

P(operator) = -ihbar. Del or in one dimension -ihbar. d/dx
as T= P^2/2m the operator form will be -hbar^2 /2m . d^2/dx^2
 
drvrm said:
check the expression for T -i think it should be hbar^2 may be a typo.
as we know the kinetic energy operator in coordinate representation is the above expression as differential operator.
it can be derived from the operator form of momentum

P(operator) = -ihbar. Del or in one dimension -ihbar. d/dx
as T= P^2/2m the operator form will be -hbar^2 /2m . d^2/dx^2

Thanks! Let me make sure I understand your explanation: squaring the p(operator) gives (-ihbar∇)^2 = -hbar^2*(∇∙∇), and ∇∙∇ = ∇^2 because the dot product of a vector with itself is equal to the magnitude of that vector squared. Therefore, T = p^2/2m = (-hbar^2/2m)∇^2. The kinetic energy of a classical wave would also be proportional to ∇^2, because the momentum of a classical wave is proportional to ∇.
 
Steven Hanna said:
Thanks! Let me make sure I understand your explanation: squaring the p(operator) gives (-ihbar∇)^2 = -hbar^2*(∇∙∇), and ∇∙∇ = ∇^2 because the dot product of a vector with itself is equal to the magnitude of that vector squared. Therefore, T = p^2/2m = (-hbar^2/2m)∇^2.
Yes.
Steven Hanna said:
The kinetic energy of a classical wave would also be proportional to ∇^2, because the momentum of a classical wave is proportional to ∇.
No, the macroscopic, nonrelativistic kinetic energy is always given by ##\frac{1}{2}mv^2##.
 
Steven Hanna said:
The formula T = -(ħ/2m)∇2 implies that T is proportional to the second spatial derivative of a wavefunction. What is the origin of this dependence?

Strange but true, and one of the deepest discoveries of modern physics, the answer is symmetry. You will find the detail in chapter 3 of Ballemtine:
https://www.amazon.com/dp/9814578584/?tag=pfamazon01-20

It involves advance math but is still worth taking a look at.

Thanks
Bill
 
drvrm said:
check the expression for T -i think it should be hbar^2 may be a typo.
as we know the kinetic energy operator in coordinate representation is the above expression as differential operator.
it can be derived from the operator form of momentum

P(operator) = -ihbar. Del or in one dimension -ihbar. d/dx
as T= P^2/2m the operator form will be -hbar^2 /2m . d^2/dx^2

You're getting close to 500 posts now. Time to learn some Latex!
 

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