Why Don't 5 Si Atoms Bind with Added Phosphorus?

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Discussion Overview

The discussion revolves around the binding behavior of phosphorus atoms when added to silicon, specifically why phosphorus binds with only four silicon atoms instead of five. The conversation touches on the lattice structure of silicon and the nature of covalent bonds within that structure.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant questions why phosphorus does not bind with five silicon atoms, suggesting that it would need to do so to utilize its extra electron.
  • Another participant points to the lattice structure of silicon, questioning the spatial feasibility of a fifth silicon atom and how it would bond with others.
  • A similar point is reiterated by another participant, who expresses uncertainty about the spatial arrangement in the lattice.
  • A participant raises a question about whether the covalent bonds among silicon atoms in the lattice can be classified as intermolecular bonds.
  • Another participant responds by clarifying that there are no molecules in the lattice, implying that the bonds should not be considered intermolecular.

Areas of Agreement / Disagreement

Participants express uncertainty regarding the binding behavior of phosphorus and the spatial arrangement of silicon atoms. There is disagreement on the classification of bonds within the lattice structure.

Contextual Notes

Limitations include assumptions about the bonding capabilities of phosphorus and the definitions of intermolecular versus intramolecular bonds, which remain unresolved.

Entanglement
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Why when phosphorus is added to silicon, phosphorus bind with only four silicon atoms and contributes with its extra electron, why doesn't just phosphorus bind with 5 silicon atoms since that is what it needs ?
 
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Look at the lattice structure of silicon: where would the 5th silicon atom be? Is there space for a 5th and how would that atom bond to other atoms?
 
mfb said:
Look at the lattice structure of silicon: where would the 5th silicon atom be? Is there space for a 5th and how would that atom bond to other atoms?
That was I thought but I wasn't sure, thanks by the way :smile:
 
One more question, Are the covalent bonds among the silicon atoms in a lattice considered as intermolecular bonds ?
 
There are no molecules in the lattice, I don't see why you would call bonds there "intermolecular bonds".
 

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