Why is the s state spherically symmetric?

In summary: This is illustrated in figure 7.3 on page 20 of the referenced document.Furthermore, in the absence of an angular momentum, the electron is said to be in a "ground state," which corresponds to a spherical shape.
  • #1
KFC
488
4
Hi there,
I am reading something about quantum numbers, there the author introduce the quantum number by solving Schrodinger equation for Hydrogen atom. It gives me an example when the principal quantum number n=4, there are four different sub-level ##s, p, d, f##. It also depicts the sublevel for them. It is said that for s state which ##\ell=0##, the shape is something like a completely flattened ellipse going through the nucleus. But since ##\ell=0##, there is no angular momentum, the electron is not "orbiting" anything; hence, it must be totally radially so s state is spherically symmetric.

It is quite confusing for me. Since it is said at the beginning it is flatten ellipse but later becomes spherically symmetric.

reference: http://web.pdx.edu/~pmoeck/lectures/312/chapter 7 part 3.doc
page 3 and page 8
 
Last edited:
Physics news on Phys.org
  • #2
KFC said:
It is said that for s state which ##\ell=0##, the shape is something like a completely flattened ellipse going through the nucleus.
Where does your reference say that?
KFC said:
But since ##\ell=0##, there is no angular momentum, the electron is not "orbiting" anything; hence, it must be totally radially so s state is spherically symmetric.
Right. s orbitals are spherically symmetric.
 
  • #3
Doc Al said:
Where does your reference say that?

Right. s orbitals are spherically symmetric.

Sorry that I give the wrong reference. I just get it corrected. And in the document given by the link, in page 3, note below the caption of FIGURE 7.3, it is said that "for l=0 we have a completely flattened ellipse that goes through the nucleus, this will be later called an s state."
 
  • #4
Those elliptical orbits are remnants of the Bohr-Sommerfeld model of the atom. (Old stuff!) Note the diagram on page 20 of your reference, which shows the s orbitals as spherical.
 
  • Like
Likes KFC
  • #5
Thanks a lot.
 
  • #6
KFC said:
Hi there,
I am reading something about quantum numbers, there the author introduce the quantum number by solving Schrodinger equation for Hydrogen atom. It gives me an example when the principal quantum number n=4, there are four different sub-level ##s, p, d, f##. It also depicts the sublevel for them. It is said that for s state which ##\ell=0##, the shape is something like a completely flattened ellipse going through the nucleus. But since ##\ell=0##, there is no angular momentum, the electron is not "orbiting" anything; hence, it must be totally radially so s state is spherically symmetric.

It is quite confusing for me. Since it is said at the beginning it is flatten ellipse but later becomes spherically symmetric.

reference: http://web.pdx.edu/~pmoeck/lectures/312/chapter 7 part 3.doc
page 3 and page 8
According to my prejudices, I always warn against physics manuscripts written with Word. This one cements my prejudice. SCNR.
 
  • #7
Classically, an orbit with l=0 corresponds to the electron falling straight on or through the nucleus. Quantum mechanically, the orientation of this line becomes completely undetermined.
 
  • #8
Quantum mechanically ##l=0## means that your wave function and thus the probability distribution for the particle's position (and momentum) is spherically symmetric.
 

1. Why is the s state spherically symmetric?

The s state is spherically symmetric because the electron probability density is distributed evenly in all directions around the nucleus. This is due to the fact that the s orbital has no angular nodes, meaning there are no areas where the electron has a zero probability of being found. As a result, the electron is equally likely to be found at any point on a spherical surface around the nucleus, making the s state spherically symmetric.

2. How does the s state differ from other atomic orbitals?

The s state differs from other atomic orbitals in terms of its shape and energy. The s orbital is spherical in shape, while other orbitals have more complex shapes such as dumbbells and pears. Additionally, the s state has the lowest energy level, meaning electrons are most likely to be found in this orbital closest to the nucleus.

3. What causes the s state to be spherically symmetric?

The spherically symmetric nature of the s state is a result of the quantum mechanical properties of electrons. In quantum mechanics, electrons are described by wavefunctions that determine the probability of finding an electron at a certain position. The lack of angular nodes in the s orbital allows the electron to be equally probable at any point on a spherical surface around the nucleus, resulting in spherically symmetric behavior.

4. Can the s state be found in all elements?

Yes, the s state can be found in all elements. All atoms have at least one s orbital, with the number increasing with the atomic number. The s orbital is the first orbital to be filled in an atom's electron configuration, and it plays a crucial role in the chemical properties of elements.

5. How does the s state contribute to the stability of an atom?

The s state contributes to the stability of an atom by allowing the electrons to be closer to the positively charged nucleus. This results in a stronger attraction between the electrons and the nucleus, which helps hold the atom together. Additionally, the s orbital is the first to be filled in an atom's electron configuration, with subsequent orbitals being filled in order of increasing energy, contributing to the overall stability of the atom.

Similar threads

Replies
5
Views
6K
  • High Energy, Nuclear, Particle Physics
Replies
1
Views
1K
  • MATLAB, Maple, Mathematica, LaTeX
Replies
7
Views
2K
  • Quantum Physics
Replies
6
Views
2K
  • Advanced Physics Homework Help
Replies
6
Views
1K
  • Quantum Physics
Replies
4
Views
5K
  • Beyond the Standard Models
Replies
0
Views
1K
Replies
1
Views
3K
  • Quantum Physics
Replies
9
Views
3K
Replies
177
Views
28K
Back
Top