Recent content by flybynight

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    Epoxide reacting with Tosylic Acid and Water

    Any suggestions for the stereochemistry of this reaction?
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    Epoxide reacting with Tosylic Acid and Water

    Homework Statement I was given the reaction in the attachment, and asked to find the product. 2. The attempt at a solution My understanding is that water can open epoxide rings, in an acidic environment. And so, I would figure that the product is 1-methyl-1,2-cyclohexanediol. I don't know...
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    PKa of 2-nitrophenol vs 3-nitrophenol

    Thanks Borek. I didn't see that one.
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    PKa of 2-nitrophenol vs 3-nitrophenol

    Homework Statement I am given the structures for 2-nitrophenol and 3-nitrophenol, and asked which one has the higher pKa and why. Homework Equations pKa=-log(Ka) The Attempt at a Solution I looked up the pKas in a reference and found the pKa of 2-nitrophenol to be 7.17 while the pKa of...
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    What are my odds? Sophomore Chemistry REU

    So, would you, the wise ones who have gone through the applications before, say that if I apply to about 10 programs, I would have a good chance of getting into at least one? I will also be applying for some on-campus research and some non-REU sites. I really, really do not want to end up doing...
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    What are my odds? Sophomore Chemistry REU

    My lab instructors are professors, so I might be able to use them as recs. I guess I'll just talk with them one-on-one to determine whether they think they can write a good letter. I did my research at a different college during high school. I guess I could go for a rec from him, as the...
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    What are my odds? Sophomore Chemistry REU

    At my school, we have different profs for class and lab. Which do you think it would be better to get recs from? I'm a little concerned that my professors don't know me well enough to write good recs because I did research with them. Is that a problem, do you think? Peter
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    What are my odds? Sophomore Chemistry REU

    Hi everyone, This summer I spent a lot of time looking at possible research sites for next summer. I was wondering if anyone out there could gauge the odds of me landing a research project. I am entering the sophomore year at St. Olaf College (a small Liberal Arts school in Southern...
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    What is the Reaction Order and Rate Constant for 2C4H6 --> C8H12 at 320°C?

    I got it. Every time the reactant is changed into product, the pressure is one half for that molecule. So I found the values of the reactants and the products, and found the order is 1. Thanks for the help, Peter
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    Similarity of Diagonalizable Matrices

    Yes, I know how to diagonalize the matrices.
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    Similarity of Diagonalizable Matrices

    Homework Statement A = {{2,1,0}{0,-2,1}{0,0,1}} and B = {{3,2,-5}{1,2,-1}{2,2,-4}} Show that A and B are similar by showing that they are similar to the same diagonal matrix. Then find an invertible matrix P such that P-1AP=B Homework Equations P-1AP=B, or AP=PB The Attempt at a...
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    What is the Reaction Order and Rate Constant for 2C4H6 --> C8H12 at 320°C?

    Homework Statement I am considering the reaction 2C4H6 --> C8H12 at 320 degrees C. Both the product and the reactant are gases. I have the data: Time (minutes): 0.00 3.25 12.18 24.55 42.50 68.05 Total P (torr): 632.0 618.5 584.2 546.8 509.3 474.6...
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    Chemical Equilibrium and Probability

    I am looking at this equilibrium: H2O + D2O <-> 2DHO (D = Deuterium) I have 2.0 mol of H2O, 1.0 mol of D2O and 2.0 mol of DHO. What are the equilibrium amounts of each of the molecules? What I tried: 6 mol of H, 4 mol of D H2O: P(X=H) & P(Y=H) = 9/25 D2O: P(X=D) & P(Y=D) = 4/25 HDO...
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