Recent content by McLaren Rulez

  1. M

    Angular momentum commutation relations

    Of course. Let's start with the ##[l_2, l_3]## commutator ## \begin{align*} \langle m, l | [l_2^2, l_3^2]| l,m \rangle &= \langle m, l | l_2^2l_3^2 - l_3^2l_2^2| l,m \rangle \\ &= \langle m, l | l_2^2l_3^2| l,m \rangle - \langle m, l | l_3^2l_2^2| l,m \rangle \\ \end{align*} ## Utilize the...
  2. M

    Angular momentum commutation relations

    I feel silly for not trying the obvious. Thank you Dr. Claude.
  3. M

    Angular momentum commutation relations

    That's okay, thank you for helping. I guess the idea is to somehow write ##l_1## and ##l_2## in terms of the ladder operators but some basic manipulations haven't really led me anywhere.
  4. M

    Angular momentum commutation relations

    That is the full question. I believe it means that the commutator acting on the state ##|l,m\rangle## i.e. ##\langle m, l| [l_i^2, l_j^2] |l, m \rangle = 0##. Of course ##l## and ##m## are the usual quantum numbers corresponding to ##L^2## and ##l_3##
  5. M

    Angular momentum commutation relations

    Homework Statement Show that ##|l, m\rangle## for ##l=1## vanishes for the commutator ##[l_i^2, l_j^2]##. Homework Equations ##L^2 = l_1^2 + l_2^2 + l_3^2## and ##[l_i^2,L^2]=0## The Attempt at a Solution I managed to so far prove that ##[l_1^2, l_2^2] = [l_2^2, l_3^2] = [l_3^2, l_1^2]##. I...
  6. M

    Degrees of freedom of harmonic oscillator

    I think I see what you mean. You're saying that the entire oscillator system moves with some energy (and this is translational kinetic energy) and the oscillations themselves carry a different and unrelated energy. This makes sense - earlier, I assumed that the kinetic energy you were talking...
  7. M

    Degrees of freedom of harmonic oscillator

    How is this different to allocating all 12J to the oscillator at rest and then releasing it? Am I then correct in transforming that to state that the amplitude and the phase are the two degrees of freedom here? I can understand how more energy leads to a larger amplitude but I'm struggling to...
  8. M

    Degrees of freedom of harmonic oscillator

    Homework Statement A three-dimensional harmonic oscillator is in thermal equilibrium with a temperature reservoir at temperature T. The average total energy of oscillator is A. ½kT B. kT C. ³⁄₂kT D. 3kT E. 6kT Homework Equations Equipartition theorem The Attempt at a Solution So I know the...
  9. M

    Undergrad Understanding Hund's Second Rule: What is a Singlet or Triplet?

    Ah I see! Thank you a million DrClaude. You've really helped me finally get it!
  10. M

    Undergrad Understanding Hund's Second Rule: What is a Singlet or Triplet?

    Thank you for the detailed document. I think I mostly get it except for how the ##L## value is known from a given ##M_L##. If I look at the microstates, for example, the fifth one in your table ##M_L = 0## but the ##L## value of this can be either ##0, 1## or ##2##. How is it that it is labelled...
  11. M

    Undergrad Understanding Hund's Second Rule: What is a Singlet or Triplet?

    Thank you. Sorry to ask more questions but how did you know that ##^3P, ^1D##, and ##^1S## were the available options? In other words, why is it that the way spin adds up also determine ##L##? For example, why can I not have ##S=1## and ##L=0## which is the state ##^3S## in spectroscopic notation?
  12. M

    Undergrad Understanding Hund's Second Rule: What is a Singlet or Triplet?

    Thank you for your reply. Can I check what exactly 3P, 1D, and 1S notation means? Sorry, if this is an obvious question but I'm guessing the 3 and the 1 refer to the triplet and the singlet but what are the P, D, and S?
  13. M

    Undergrad Understanding Hund's Second Rule: What is a Singlet or Triplet?

    Can anyone explain the second rule, because the Wikipedia page is not very clear? Hund's zeroth rule - Ignore all inner shells and focus on the outermost shell. Hund's first rule - Put the electrons such that they maximize spin, ##s##. So far so good. Hund's second rule appears to be simply...
  14. M

    Graduate Deriving the thermodynamic beta from Lagrange Multipliers

    I'm nearly at the end of this derivation but totally stuck so I'd appreciate a nudge in the right direction Consider a set of N identical but distinguishable particles in a system of energy E. These particles are to be placed in energy levels ##E_i## for ##i = 1, 2 .. r##. Assume that we have...
  15. M

    Undergrad Infinite square well solution - periodic boundary conditions

    I meant the stationary states so only energy is allowed