How Is Entropy Calculated for a Multi-Energy Level System?

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Entropy for a multi-energy level system can be calculated using the partition function, which is defined as Z = 1 + exp(-ε/τ) + exp(-2ε/τ). The Helmholtz free energy is given by F = -τ log(Z), and the entropy can be derived from it using the relation σ = - (∂F/∂τ). Concerns were raised about the correct application of the partition function, specifically whether to use Z or Z^N/N!. The discussion concluded that using Z = Z_1^N/N! would yield the correct expression for entropy in this context.
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Homework Statement


A system of particles is in equilibrium at temperature T. Each particle may have energy 0, epsilon, or 2 epsilon. Find the entropy of the system.

Homework Equations



F=-\tau log(Z)

\sigma=-(\frac{\partial\sigma}{\partial\tau})|_{V}

The Attempt at a Solution



<br /> <br /> Z = 1+exp(\frac{-\epsilon}{\tau})+exp(\frac{-2\epsilon}{\tau})<br />

F=-\tau log(1+exp(\frac{-\epsilon}{\tau})+exp(\frac{-2\epsilon}{\tau}))

\sigma=-log(1+exp(\frac{-\epsilon}{\tau})+exp(\frac{-2\epsilon}{\tau}))-\tau\frac{[\epsilon\tau^{-2}exp(-\epsilon/\tau)+2\epsilon\tau^{-2}exp(-2\epsilon/\tau)]}{1+exp(\frac{-\epsilon}{\tau})+exp(\frac{-2\epsilon}{\tau})}

Hows that look? I'm really rusty with my thermal physics so even though this is not very complicated, I just have no confidence. One thing I was worried about was my partition function. When is the function I used applicable, and when do I need to use

Z_{N}=\frac{Z^{N}_{1}}{N!}?

As I type this I am becoming increasing doubtful that I used the right partition function. Thanks for reading!
 
Last edited:
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Is my question ill posed? Please if you read this say anything, say whatever you think even if you don't know.
 
Now I am feeling rather sure that all I need to do is replace my Z with Z^N and I have my answer. Any thoughts?
 
Anyone? Anything?

I just noticed a mistake in my first post, the second equation should be sigma=(partial F)/(partial tau). But if you can help me you probably knew that already...
 
Using Z = Z_1^N/N! , you should get the correct expression.
 

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