Why does the gas with the smallest molar mass have the highest pressure?

Click For Summary
SUMMARY

The discussion centers on the relationship between molar mass and gas pressure, specifically comparing Xenon, Argon, and Neon in equal mass scenarios. The conclusion is that Neon, having the smallest molar mass, results in the highest pressure due to the greater number of moles present. This is derived from the ideal gas law, expressed as P = (RnT)/V, where the number of moles (n) is inversely proportional to molar mass (m). Thus, for equal masses, the gas with the smallest molar mass yields the highest pressure.

PREREQUISITES
  • Understanding of the ideal gas law (PV = nRT)
  • Knowledge of molar mass and its implications in gas behavior
  • Familiarity with the concept of moles in chemistry
  • Basic principles of gas pressure and volume relationships
NEXT STEPS
  • Study the ideal gas law in depth, focusing on its applications and derivations.
  • Explore the concept of molar mass and its effect on gas properties.
  • Investigate real-world applications of gas laws in various scientific fields.
  • Learn about the kinetic molecular theory and its relation to gas behavior.
USEFUL FOR

Chemistry students, educators, and professionals in scientific fields who require a solid understanding of gas laws and their applications in real-world scenarios.

codcodo
Messages
11
Reaction score
0

Homework Statement


If equal masses of Xenon, Argon and Neon are placed in separate flasks of equal volume and same temperature, which one of the following statements is correct:
a) The pressure of Neon flask is greatest.
b) The pressure of Argon flask is greatest.
c) The pressure of Xenon flask is greatest.
d) The pressure in all 3 flasks is the same.

Homework Equations


None

The Attempt at a Solution


The answer stated was Neon because it contains the smallest molar mass out of the three. The smallest molar mass will contain the greatest number of moles. Since pressure is directly proportional to the number of moles in a gas, the pressure of Neon flask is the greatest.

I know that the pressure is directly proportional to the number of moles. But why does the smallest molar mass contain the greatest number of moles?
 
Last edited:
Physics news on Phys.org
Because it says equal masses of each gas are in the flask. If you have two piles with the same mass, and one pile consists of bowling balls and one consists of ping-pong balls, which pile has more balls?
 
  • Like
Likes   Reactions: codcodo
Ping-pong balls! Thank you for the wonderful analogy. It makes perfect sense now.
 
codcodo said:

Homework Equations


None
Just to point out that there is a relevant equation. The ideal gas law ##PV = RnT##. You can rewrite this as
$$
P = \frac{RnT}{V}.
$$
Since ##n = M/m##, where ##m## is the molar mass and ##M## is the total mass, you would find
$$
P = \frac{RMT}{V} \frac{1}{m}.
$$
Since ##R##, ##M##, ##T##, and ##V## were assumed to be the same, the gas with the smallest molar mass ##m## will have the highest pressure.
 
  • Like
Likes   Reactions: codcodo
Orodruin said:
Since ##n = M/m##, where ##m## is the molar mass and ##M## is the total mass

Funny, I would switch M and m (using the capital letter to mark molar mass and the small one for the gas mass). I feel like it is an accepted convention (but I can be wrong).
 
  • Like
Likes   Reactions: codcodo
Borek said:
Funny, I would switch M and m (using the capital letter to mark molar mass and the small one for the gas mass). I feel like it is an accepted convention (but I can be wrong).
That may be, it is not my direct field so I may have introduced conventions contrary to what is usually used. Of course, the notation has no impact on the physics.
 
@Orodruin Sure thing, what you wrote is perfectly correct. Actually I thought about posting exactly the same, just assumed OP already got it.
 
Borek said:
Funny, I would switch M and m (using the capital letter to mark molar mass and the small one for the gas mass). I feel like it is an accepted convention (but I can be wrong).

I use M for molar mass and m for gas mass.
 
Orodruin said:
Just to point out that there is a relevant equation. The ideal gas law ##PV = RnT##. You can rewrite this as
$$
P = \frac{RnT}{V}.
$$
Since ##n = M/m##, where ##m## is the molar mass and ##M## is the total mass, you would find
$$
P = \frac{RMT}{V} \frac{1}{m}.
$$
Since ##R##, ##M##, ##T##, and ##V## were assumed to be the same, the gas with the smallest molar mass ##m## will have the highest pressure.
Thank you.
 

Similar threads

  • · Replies 16 ·
Replies
16
Views
3K
  • · Replies 10 ·
Replies
10
Views
5K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 2 ·
Replies
2
Views
4K
Replies
3
Views
6K
  • · Replies 2 ·
Replies
2
Views
5K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 2 ·
Replies
2
Views
13K
Replies
3
Views
2K