A relation to Le-chatelier's principle?

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SUMMARY

The discussion centers on the chemical reaction between iron (Fe) and hydrochloric acid (HCl) that produces iron(II) chloride (FeCl2) and hydrogen gas (H2). Participants confirm that the liberation of H2 shifts the reaction equilibrium towards the products, thereby favoring the formation of FeCl2 over iron(III) chloride (FeCl3). The reasoning is rooted in Le Chatelier's principle, which states that removing a product (H2) drives the reaction to produce more products. Additionally, the stability of the +2 oxidation state of iron is highlighted as a contributing factor to the preference for FeCl2.

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  • Understanding of Le Chatelier's principle
  • Basic knowledge of chemical equilibrium
  • Familiarity with oxidation states, particularly iron(II) and iron(III)
  • Knowledge of chemical reaction equations
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mooncrater
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Homework Statement


We know about the equation:
##Fe+2HCl(g) \longrightarrow FeCl_2+H_2##. In my textbook it's written that liberation of ##H_2## prevents formation of ##FeCl_3##.
But why?And how?

Homework Equations

The Attempt at a Solution


I think it is related to the Le-Chatelier principle . As ##H_2## is liberated more, the reaction equilibrium is shifted towards the products . So more ##FeCl_2## will be produced. But for ##FeCl_3##, I think there should be an alternative path for the reactants to produce ##FeCl_3## along with the path producing ##FeCl_2## and ##H_2##. I think this path is neglected when the reaction equilibrium is shifted towards the products of the other path.Am I correct , or is there any other reason for that?
 
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I think you're right. As you take away product, more product is formed. As far as an alternate route goes, the reaction could go Fe + 3HCL = FeCl3 + 3/2H2. If you are constantly taking away H2 then the reaction should constantly be shifting to the right and keeping the FeCl3 from forming.
 
leafjerky said:
I think you're right. As you take away product, more product is formed. As far as an alternate route goes, the reaction could go Fe + 3HCL = FeCl3 + 3/2H2. If you are constantly taking away H2 then the reaction should constantly be shifting to the right and keeping the FeCl3 from forming.
I think the reaction I am talking about forms ##FeCl_2## not## FeCl_3##.
Though ##H_2## is liberated in both the reactions why ##FeCl_2## formation is preferred? Is it due to the reason that ##Fe^{+2}## is the most stable o. S. Of ##Fe##. I am leaving the Le-chatelier approach, as it is working for both
 

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