Are intermolecular and van der waals forces the same?

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Discussion Overview

The discussion revolves around the relationship between intermolecular forces and van der Waals forces, particularly in the context of surface tension. Participants explore various types of forces involved, including hydrogen bonding and the implications of electromagnetic interactions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Homework-related

Main Points Raised

  • One participant questions whether intermolecular forces and van der Waals forces are the same, seeking clarification for a physics assignment on surface tension.
  • Another participant explains that all relevant forces are electromagnetic, noting that van der Waals forces arise from dipole interactions in neutral atoms, which are generally weak due to their rapid fall-off with distance.
  • A different participant suggests that classical electromagnetism may not fully explain all electromagnetic forces, proposing that quantum field theory (QFT) might be necessary for a complete understanding, particularly in relation to surface tension.
  • One participant references a specific textbook that discusses van der Waals forces and surface tension, suggesting it may contain useful information.
  • There is a question about whether an external electric field can modify the van der Waals effect, with some participants indicating that it could necessitate a modification of the original descriptions of these interactions.
  • Another participant expresses uncertainty about whether the question regarding the electric field should be a new thread or if it should wait for more responses to the original inquiry.

Areas of Agreement / Disagreement

Participants express differing views on the relationship between intermolecular forces and van der Waals forces, as well as the adequacy of classical electromagnetism versus quantum field theory in explaining these interactions. The discussion remains unresolved with multiple competing perspectives.

Contextual Notes

Some participants note the limitations of classical explanations and the potential need for quantum approaches, indicating that the discussion may depend on specific definitions and assumptions about the forces involved.

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are intermolecular an van der waals forces the same thing? I am doing a physics assignment on surface tension and am unsure of what forces are present. i know that there is hydrogen bonding, but what else? thanks
 
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all the forces of interest are ultimately electromagnetic.

van der waals forces are a way for atoms which are overall neutral to still interact and are due to the fact that even a neutral atom can have a dipole moment, and the interaction of two dipole falls off like the sixth power of the distance. So those forces are generally considered weak (since they fall off fast) compared to forces between charged things.

P.S. if there's a homework assignment related to this question then maybe this thread should have been posted in the homework forums...
 
While all the forces of interest are ultimately electromagnetic, it's not clear that they can all be explained with classical electromagnetism. One may need to go to quantum field theory to explain all the details of electromagnetic forces. The Casimir force is a good example of a force explainable only with QFT. I know that surface tension was a mystery for a long time, suggesting to me that it's explanation may require more than classical E&M (otherwise it wouldn't have been such a mystery).

I recall hearing that QFT resolved some of the questions with surface tension, but I don't recall where I read this, it may not have been a reliable source :-(.

Sorry to post when I don't have a definite confirmed answer, but I think the question is an interesting one, and I'd like to get a better handle on it myself.
 
BTW, Chaiken and Lubensky's Solid State book discusses van der waals forces in one of the first few chapters. Probably has a lot of good stuff on surface tension, etc.
 
Can application of an outside E-field modify the van der Waals effect?
 
Are you asking me, or pervect? Should this question be a new thread? The OP hasn't had much of a chance to respond yet to the answers given to his question...
 
It certainly can wait until more responses address the original concern.
 
Loren Booda said:
Can application of an outside E-field modify the van der Waals effect?

Certainly applying an external electric field will have an effect on a collection of atoms and the description of the interactions will have to account for it... the original description, if in terms of van der waals alone, should have to be modified.
 

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