Van der Waals' Forces and Hydrogen Bonding

In summary, the distinction between Van der Waals' forces and hydrogen bonds is not always clear-cut, as some bonds fall somewhere in between. While compounds like HF typically form hydrogen bonds and compounds like HCl form Van der Waals' forces, there are cases where the bond behavior may not be as expected, such as in HCl where H is delta positive and Cl is delta negative. Overall, the formation of Van der Waals' forces and hydrogen bonds depends on the specific characteristics of the compounds involved.
  • #1
Priyadarshini
191
4
Induced dipoles result in Van der Waals' forces and permanent dipoles in hydrogen bonds, right? But how do you know is a compound has formed hydrogen bonds or Van der Waals' forces? For example, HF forms hydrogen bonds while HCl forms Van der Waals' forces and not hydrogen bonds. But in HCl, H is delta positive and Cl is delta negative, so shouldn't it form hydrogen bonds? But then when do Van der Waals' forces form?
Thanks.
 
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  • #2
Those categories don't have a sharp dividing line. Some bonds are very van-der-Waals-like, some are very hydrogen-bond-like, some are somewhere in between.
 
  • #3
mfb said:
Those categories don't have a sharp dividing line. Some bonds are very van-der-Waals-like, some are very hydrogen-bond-like, some are somewhere in between.
Oh, thanks!
 

1. What are Van der Waals' Forces and Hydrogen Bonding?

Van der Waals' Forces and Hydrogen Bonding are two types of intermolecular forces that exist between molecules. They are responsible for holding molecules together in liquids and solids.

2. What is the difference between Van der Waals' Forces and Hydrogen Bonding?

The main difference between Van der Waals' Forces and Hydrogen Bonding is the strength of the force. Van der Waals' Forces are relatively weak and are caused by temporary dipoles in molecules, while Hydrogen Bonding is a stronger force that occurs between molecules with a hydrogen atom bonded to a highly electronegative element (such as oxygen or nitrogen).

3. How do Van der Waals' Forces and Hydrogen Bonding affect the properties of substances?

Van der Waals' Forces and Hydrogen Bonding play a crucial role in determining the physical properties of substances. For example, substances with strong Hydrogen Bonding, such as water, have higher boiling points and surface tension compared to substances with weaker Van der Waals' Forces.

4. Can Van der Waals' Forces and Hydrogen Bonding be seen or measured?

No, Van der Waals' Forces and Hydrogen Bonding cannot be seen or measured directly. However, their effects can be observed through changes in physical properties, such as boiling point, melting point, and surface tension.

5. How do Van der Waals' Forces and Hydrogen Bonding contribute to the structure of biological molecules?

Van der Waals' Forces and Hydrogen Bonding play a crucial role in the structure of biological molecules, such as proteins and DNA. These forces help to hold the molecules together in specific shapes, which is essential for their function in living organisms.

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