Are Sodium Acetate and Sodium Cyanide Solutions Acidic or Basic?

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SUMMARY

The discussion clarifies that sodium acetate and sodium cyanide solutions are not acidic despite their association with acetic acid and hydrocyanic acid, respectively. In 0.1 M solutions, the hydroxide ion concentration ([OH-]) in sodium acetate is lower than that in sodium cyanide, confirming that sodium acetate is a weaker base. The misconception that [H+] exceeds [OH-] in these solutions is addressed, emphasizing that sodium acetate and sodium cyanide are Brønsted-Lowry bases, not acids.

PREREQUISITES
  • Understanding of Brønsted-Lowry acid-base theory
  • Knowledge of ionization constants (Ka and Kb)
  • Familiarity with the properties of conjugate acids and bases
  • Basic chemistry concepts regarding pH and pOH calculations
NEXT STEPS
  • Research the ionization constants of acetic acid (Ka = 1.8E-5) and hydrocyanic acid (Ka = 4E-10)
  • Study the concept of conjugate acid-base pairs in detail
  • Learn how to calculate pH and pOH in weak acid and base solutions
  • Explore the implications of Brønsted-Lowry theory in various chemical reactions
USEFUL FOR

Chemistry students, educators, and professionals seeking to deepen their understanding of acid-base chemistry and the behavior of conjugate bases in solution.

Jules18
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Here's the question:

The ionization constant for acetic acid is 1.8E-5; that for hydrocyanic acid is 4E-10. In 0.1 M solutions of sodium acetate and sodium cyanide, it is true that:

And the answer is:

[OH-] of the sodium acetate solution is less than that of the sodium cyanide solution.

Which makes sense to me, because acetic acid is the stronger acid. But there's another option in the list that it says is NOT true:

[H+] exceeds [OH-] in each solution.

I thought this might be true, because both are solutions of chemicals that were referred to as acids.
Am I missing the definition of an acid?
 
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Jules18 said:
I thought this might be true, because both are solutions of chemicals that were referred to as acids.
Am I missing the definition of an acid?

That would be true if they were talking about solutions of acetic acid or hydrocyanic acid. However, they are talking about solutions of sodium acetate and sodium cyanide, the conjugate bases of the aforementioned acids.
 

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