Assumptions Built in to Solving Titration Equilibria?

Click For Summary
SUMMARY

This discussion focuses on the assumptions involved in calculating equilibrium concentrations in titration equilibria, specifically when mixing equal concentrations of NH3 and HCl. The primary assumption is that HCl fully ionizes, allowing the reaction NH3 + H3O+ → NH4+ + H2O to proceed without considering the presence of residual H3O+ ions. The participant raises concerns about the simplifications made in equilibrium calculations and suggests using resources like ChemBuddy for a more comprehensive understanding of acid/base equilibria without assumptions.

PREREQUISITES
  • Understanding of acid-base chemistry, specifically the behavior of strong acids like HCl and weak bases like NH3.
  • Familiarity with equilibrium concepts, including ICE (Initial, Change, Equilibrium) tables.
  • Knowledge of acid dissociation constants (Ka) and their application in equilibrium calculations.
  • Basic proficiency in using online chemistry resources for problem-solving.
NEXT STEPS
  • Explore the concept of acid-base equilibrium using the ChemBuddy pH calculation tool.
  • Study the implications of residual H3O+ ions in equilibrium calculations.
  • Learn about the assumptions made in different types of equilibrium problems, particularly in weak acid/base scenarios.
  • Investigate the application of the Henderson-Hasselbalch equation in buffer solutions and equilibrium calculations.
USEFUL FOR

Chemistry students, educators, and professionals involved in analytical chemistry or titration experiments who seek a deeper understanding of equilibrium assumptions and their implications in acid-base reactions.

QuestionMarks
Messages
64
Reaction score
0
I'm trying to reach a more thorough understanding of what's going on when we calculate equilibrium concentrations and was wanting to understand more what assumptions we make in order to follow through with the calculations.

Let me ask off of an example:
Consider mixing equal amounts of NH3 and HCl, each having the concentration of α upon mixing.

The general way I've seen taught is to assume via being a strong acid that the HCl fully ionizes and causes the following equation to occur:
NH3 + H30+ → NH4+ + H2O
Then to recognize that NH4+ is a weak acid, so we'll need to set up the reverse equation as an equilibrium to run an ICE problem off of:
NH4+ + H2O ←→ NH3 + H30+
Wherein we take the initial concentration of NH4+ to be α, and can use it's Ka to find the final hydrogen ion concentration of the entire solution.

Here then are my questions directly:
1) In the first equation, we seem to assume that all the hydrogen ions from HCl jump onto our NH3, thus allowing us to use our initial α concentration also as the initial concentration of NH4+. How so? Could it not be that some hydrogen ions tend to stick around as H30+, thereby reducing the actual concentration of NH4+ to slightly less than α? What knowledge/assumptions do we use to reduce this complexity from our calculations?
2) Are there any other important assumptions we make when working similar equilibrium problems? As I work them myself, I constantly feel like the scenarios are a bit oversimplified (even if I acknowledge they give us answers very proximal to reality).

Thanks much!
 
Chemistry news on Phys.org
Reasonable time for me to bump?
 
I strongly suggest you go through the http://www.chembuddy.com/?left=pH-calculation&right=toc

Not only it shows how to solve the general case of acid/base equilibrium without any simplifying assumptions, but it also shows what the simplifications are in practical working of many cases. Once you know what the general approach is you should be able to understand why and when simplifying assumptions work (and when and why they don't).
 
I came.across a headline and read some of the article, so I was curious. Scientists discover that gold is a 'reactive metal' by accidentally creating a new material in the lab https://www.earth.com/news/discovery-that-gold-is-reactive-metal-by-creating-gold-hydride-in-lab-experiment/ From SLAC - A SLAC team unexpectedly formed gold hydride in an experiment that could pave the way for studying materials under extreme conditions like those found inside certain planets and stars undergoing...

Similar threads

  • · Replies 5 ·
Replies
5
Views
3K
Replies
3
Views
2K
Replies
11
Views
3K
  • · Replies 8 ·
Replies
8
Views
2K
Replies
9
Views
17K
  • · Replies 4 ·
Replies
4
Views
1K
  • · Replies 6 ·
Replies
6
Views
2K
  • · Replies 8 ·
Replies
8
Views
3K
  • · Replies 3 ·
Replies
3
Views
3K
Replies
2
Views
4K