Atomic Chain in BCC - # Atoms/Unit Length & Area

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Homework Help Overview

The original poster seeks to determine the number of atoms per unit length for an atomic chain in the [1 1 1] direction of a body-centered cubic (BCC) structure, as well as the number of atoms per unit area in the (1 1 1) plane. There is uncertainty regarding the definition of "atomic chain" in this context.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants discuss the contribution of corner and center atoms to the total count, questioning whether to consider fractions of atoms or whole atoms. There is also a discussion about the terminology used, specifically the difference between "atomic chain" and "atomic lattice."

Discussion Status

Some participants have provided insights into the structure of BCC and the distribution of atoms within the unit cell. However, there remains a lack of consensus on the interpretation of the terms and the exact counting method for atoms in the specified directions and planes.

Contextual Notes

Participants note the complexity of the BCC structure and the implications of shared atoms in different lattice positions. There is mention of external resources for further clarification, but no definitive resolution has been reached regarding the original poster's questions.

madeinmsia
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i'd like to know what is the number of atoms per unit length for an atomic chain in the [1 1 1] direction of a BCC structure.

i can figure out the unit length, however I'm not sure how many atoms to use. Is it 1/8+1/8+1? That means 1/8s for the two corner atoms and 1 atom for the middle? or is it just 3 atoms?

part of the problem is i cannot find anywhere the meaning of atomic chain in the BCC structure.

likewise, what if i had to find the number of atoms per unit area in the (1 1 1) plane? the area part is easy, but again is the number of atoms 4 or 1/8 * 3 + 1?
 
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What does one mean by 'atomic chain'? We usually refer to an 'atomic lattice', in which the atoms are located at specific points in a repeated crystal structure.

In a BCC cube, there is one whole atom at the center of the unit cube, and 1/8 atom at each corner of the cube.
 
i'm not sure but that's what i was asked.

so if it's atomic lattice, then i would be right to say the corners are 1/8 and the middle is 1 atom? but isn't the middle atom shared by other diagnoal lattice?
 
madeinmsia said:
i'm not sure but that's what i was asked.

so if it's atomic lattice, then i would be right to say the corners are 1/8 and the middle is 1 atom? but isn't the middle atom shared by other diagnoal lattice?
In a sense yes. One could shift the unit cell diagonally in any of the 8 directions of the BCC unit cell, and the corner atom becomes a center atom, and center atom is now a corner atom.

The unit cell is a 3D concept, as opposed to a 2D-plane.

The diagonal length is BCC unit cell is R + 2R + R, where R is the atomic radius, because the corner atoms are tangent to the center atoms. So the cubic unit cell must have a face side length of less than 2R.

http://www.science.uwaterloo.ca/~cchieh/cact/c123/bcc.html

Nice pictures here - http://www.ndt-ed.org/EducationResources/CommunityCollege/Materials/Structure/metallic_structures.htm

http://genchem.chem.wisc.edu/lab/winss/metal_cells/body_centered_cubic_metals/dim_bbc_unit_cell.htm
 
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