Balancing Redox Reaction: FeS2+Na2O2→Na2FeO4+Na2SO4+Na2O"

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Discussion Overview

The discussion revolves around balancing a redox reaction involving iron disulfide (FeS2) and sodium peroxide (Na2O2) to produce sodium ferrate (Na2FeO4), sodium sulfate (Na2SO4), and sodium oxide (Na2O). Participants explore the methodology for balancing the reaction, particularly focusing on the electron transfer and the application of stoichiometric coefficients.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant presents a semi-reaction approach to balance the electrons involved in the redox process, suggesting a multiplication factor for the oxygen reaction.
  • Another participant questions the method used, proposing an alternative approach to balance the overall reaction using coefficients for each species.
  • A later reply confirms that the multiplication factor applies to both sides of the semi-reaction but indicates a preference for balancing only the right-hand side in their approach.

Areas of Agreement / Disagreement

Participants express differing views on the methodology for balancing the reaction, with no consensus reached on the preferred approach. Some support the semi-reaction method, while others advocate for a more traditional coefficient-based balancing method.

Contextual Notes

Participants do not fully resolve the implications of multiplying the coefficients on both sides of the semi-reaction, leaving some assumptions about the balancing process unaddressed.

DottZakapa
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Homework Statement
Balance redox reaction
Relevant Equations
FeS2+Na2O2->Na2FeO4+Na2SO4+Nao
FeS2+Na2O2->Na2FeO4+Na2SO4+Na2O

Fe2+ --->Fe+6+4e-
2S-1 --->2S+6+14e-
2O- + 2e- ---> 2O
The first two have a total of 18 electrons so
In order to balance the electrons i should multiply by 9 the third semireaction
(2O- + 2e- ---> 2O-2)x9

now this 9 is going to multiply the left hand in the semi reaction equation, isn't also multiplying the right hand side?
 
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It is, yes. But is this really the way you want to handle this ? Why not solve for $$a\text{A}+b\text{B}\rightarrow c\text{C}+d\text{D} + e\text{E}\ ?$$
 
DottZakapa said:
...now this 9 is going to multiply the left hand in the semi reaction equation, isn't also multiplying the right hand side?
Yes
 
sorted
i multiply by 9 just the right hand side
while i balance as usual the left hand side due to the multiple presence of the oxygen
 

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