Deriving Even Function Solutions to TISE

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SUMMARY

The discussion focuses on proving that if the potential function V(x) is even, then the wave function solution ψ(-x) to the time-independent Schrödinger equation (TISE) is also a valid solution for the same energy E and potential V. Participants emphasize the importance of substituting x with -x in the Schrödinger equation and leveraging the property V(-x) = V(x) to demonstrate that ψ(-x) satisfies the equation. Additionally, the need to establish that the energies are nondegenerate is highlighted as a crucial part of the proof.

PREREQUISITES
  • Understanding of the time-independent Schrödinger equation (TISE)
  • Familiarity with the concept of parity in quantum mechanics
  • Knowledge of eigenvalues and eigenvectors in quantum systems
  • Basic calculus, particularly second derivatives
NEXT STEPS
  • Study the implications of parity invariance in quantum mechanics
  • Learn about the properties of eigenvalues and eigenvectors in the context of the Hamiltonian operator
  • Explore examples of even and odd solutions to the Schrödinger equation
  • Investigate the conditions for nondegeneracy of energy levels in quantum systems
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Quantum physicists, students studying quantum mechanics, and anyone interested in the mathematical foundations of the Schrödinger equation and its solutions.

broegger
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Suppose that \psi (x) is some solution to the time-independent Schrödinger equation;

-\frac{h^2}{2m}\frac{\partial^2\psi(x)}{\partial x} + V(x)\psi(x) = E\psi(x).​

I want to show that if the potential V(x) is an even function, then \psi(-x) is also a solution to same equation (same E and V).

I know I'm supposed to combine the facts that \psi(x) is a solution and that V(x) = V(-x), but I can't see how. I've noted that

\frac{\partial^2\psi(-x)}{\partial x} = \frac{\partial^2\psi(x)}{\partial x},​

but that's pretty much it :confused:
 
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Your last formula contains 2 typo's.You may want to repair it,because it's pretty important to the proof itself...

Daniel.
 
Try simply making the substitution x\to-x in the SWE, then using the fact that V(-x)=V(x). The new form should then show directly that \psi(-x) is a solution as well, since it satisfies the wave equation.
 
Yes,the way it's written and the condition imposed upon the potential energy,then the total Hamiltonian is parity invariant and of course the parity operator and the Hamiltonian commute,ergo they admit a complete set of eigenvectors...End proof... :wink:

Daniel.
 
The proof also needs to show that the energies are nondegenerate.
 
Galileo said:
The proof also needs to show that the energies are nondegenerate.

What?Please,explain...I may be tired and i may not see it...

Daniel.
 
dextercioby said:
What?Please,explain...I may be tired and i may not see it...

Daniel.
Nevermind. I didn't read the actual question. I thought it said 'every solution to the SE is either even or odd'.
 
I've tried the substitution-thing - that was my first approach, I couldn't make it work. I'm too tired now, maybe I'll work it out tomorrow - thanks for your replies.
 
Weird,the way i see it,it's immediate... :rolleyes: Anyway,i see that u didn't noticed.
\frac{\partial^{2} \psi}{\partial x}

is not correct.An essential "2" is missing...

Daniel.
 
  • #10
Oh, yea, of course. My problem is that I don't know exactly what to end up with actually. Should I prove this:

\frac{\partial^2\psi(-x)}{\partial x^2} + V(x)\psi(-x) = E\psi(-x)​

or this:

\frac{\partial^2\psi(-x)}{\partial x^2} + V(-x)\psi(-x) = E\psi(-x)​

The essential difference being the minus in the potential function. Maybe it's because I'm tired (I am!), but I can't quite figure out?
 
  • #11
They're equal,because the potential is parity invarint,viz.
V(x)=V(-x)

Daniel.
 
  • #12
Oh, yea, I'm going to lie down now :smile:
 

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