Behavioural characteristics of Titanium & Graphite

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SUMMARY

The discussion focuses on the tribological characteristics of titanium and graphite in high-temperature environments. It establishes that graphite requires minimal moisture to maintain its lubricity; otherwise, it becomes abrasive. The interaction between titanium and graphite at elevated temperatures can lead to rapid wear, as the graphite may damage the titanium's native TiO2 layer, exposing it to oxidation and forming titanium carbide (TiC). The performance of this combination is influenced by factors such as speed, load, temperature, and atmospheric composition.

PREREQUISITES
  • Understanding of tribology and wear mechanisms
  • Familiarity with high-temperature lubrication techniques
  • Knowledge of titanium and its oxidation properties
  • Awareness of graphite's lubrication requirements
NEXT STEPS
  • Research high-temperature lubricants, specifically copper-based options
  • Study the effects of environmental conditions on tribological performance
  • Examine the formation and properties of titanium carbide (TiC)
  • Explore the impact of speed and load on wear rates in tribological pairs
USEFUL FOR

Engineers, materials scientists, and tribologists interested in the performance of titanium and graphite in high-temperature applications.

AB_type_S
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Hi all,

Does anybody have any experience with titanium and graphite in terms of friction and wear over time in a relatively high temperature environment?
I realize that galvanic corrosion shouldn't be too much of an issue, but I was wondering from a sort of tribological point of view.
Hope this makes sense
Thanks in advance
 
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AB_type_S said:
Hi all,

Does anybody have any experience with titanium and graphite in terms of friction and wear over time in a relatively high temperature environment?
I realize that galvanic corrosion shouldn't be too much of an issue, but I was wondering from a sort of tribological point of view.
Hope this makes sense
Thanks in advance

Graphite depends on having minuscule amounts of water in its environment to maintain its lubricity. In a very dry environment or one hot enough to drive off intercalated water, it becomes quite abrasive. This was first found, IIRC, in WWII when graphite brushes in electric motors flown at then-novel high altitudes ( = very dry air) started chewing into the commutator metal.

Titanium against graphite at high temperatures is likely to wear fairly fast. I speculate the graphite will damage the native TiO2 layer, which will expose underlying Ti to further oxidation and to reaction with the graphite. Ti forms TiC fairly readily at elevated temperatures. There are copper-based high temperature lubricants that might work for you.

The tribological performance of Ti/graphite depends on speeds, loads, etc. as well as temperature and atmosphere composition. If the environment is other than air, my comment is not likely to apply.
 

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