Best oxidizing and reducing agent in periodic table

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SUMMARY

The best oxidizing agent in the periodic table is Fluorine, recognized for its highest electronegativity, making it an effective electron attractor. The best reducing agent is debated, with Lithium initially suggested, but Francium and Caesium also being considered due to their ionization energies and atomic sizes. Fluorine's ability to oxidize nearly all elements confirms its status, while Lithium's polarizing cation properties contribute to its reducing capabilities. However, the discussion highlights that Caesium may be a stronger reducing agent than Lithium due to its larger atomic size.

PREREQUISITES
  • Understanding of oxidation and reduction concepts
  • Familiarity with periodic table trends, including electronegativity and ionization energy
  • Knowledge of electron affinity and its implications for oxidizing agents
  • Basic chemistry terminology related to cations and anions
NEXT STEPS
  • Research the properties of Fluorine as an oxidizing agent in chemical reactions
  • Investigate the reducing capabilities of Lithium compared to Francium and Caesium
  • Explore the concept of electron affinity and its role in determining oxidizing agents
  • Study periodic trends in ionization energy and their effects on reducing agents
USEFUL FOR

Chemistry students, educators, and professionals interested in redox reactions and the properties of elements in the periodic table.

aisha
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I need to find the best oxidizing and reducing agent in the periodic table and say why i chose what i chose.

I think the best oxidizing agent is Fluorine

and the best reducing agent is Lithium I am not sure if my predictions are correct and if they are I don't know how to explain why I chose them.

Can someone please help me out?
 
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What does oxidation and reduction mean?
How did you come to chose those particular elements?
 
Fluorine is the most electronegative element.
 
how did you came up with lithium & florine?

do you think your answer makes sense?
 
If I understood your question correctly, I think the two extremes would be francium and flourine.
 
Fluorine is correct. It has the greatest electronegativity and hence is a strong electron attractor. By a similar reasoning, try and figure out the other answer (it is not lithium).

Edit : Just realized this is over a month old :redface:
 
Hi! Its nice to meet all of you!
I'm not sure I understand why fluorine is a strong oxidising agent... Isnt oxidation loss of electrons? Doesnt fluorine gain electrons? When fluorine pulls electrons to itself doesn't it increase in oxidation number meaning that it becomes oxidised and hence the reducing agent?
 
Oxidizing agent gets reduced, but it oxidizes something else. Similarly in the case of reduction - reducing agent reduces something, and it gets oxidized in the process.

Fluorine oxidizes almost everything - so it is a good oxidizing agent.

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methods
 
  • #10
You are right with Fluorine being the best oxidizing agent and your predictions of lithium being the best reducing agent is also is correct. Now it is true that Francium has the lowest ionization energy, but due to its large size it has a less polarizing cations, thus it is not the best reducing agent. Lithium relatively high ionization energy is counteracted by the large amount of energy released when the unusually small, highly polarizing Li+ cation interacts with the surrounding water molecules.
 
  • #11
I'm glad we finally got that straightened out...
 
  • #12
i think fluorine repels the incoming electron due to thick electronic cloud.
the best answer to me is chlorine. because chlorine has maximum electron affinity in periodic table.
the second answer to me is caesium.. as reducing agent means which give electron easily, so i think caesium gives the electron much easily than lithium due to big size of caesium.
 

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