Bond Orders of Isoelectronic Species

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SUMMARY

Isoelectronic species, such as F2 and O2-2, exhibit the same bond order due to their equivalent number of valence electrons and molecular orbital configurations. The bond order can be calculated using Molecular Orbital Theory with the formula: Bond Order = [(number of electrons occupying bonding orbitals) - (number of electrons in anti-bonding orbitals)] / 2. For O2, O2-, and O2-2, the bond order is consistently determined to be 1. Understanding these concepts is crucial for grasping the stability and reactivity of these molecules.

PREREQUISITES
  • Molecular Orbital Theory (MOT)
  • Bonding and anti-bonding orbitals
  • Valence electron configuration
  • Basic principles of chemical bonding
NEXT STEPS
  • Learn how to calculate bond order for various molecules using Molecular Orbital Theory.
  • Study the differences in bond order among isoelectronic species.
  • Explore the concept of anti-bonding orbitals in detail.
  • Refer to standard inorganic chemistry textbooks for comprehensive understanding of MOT.
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Chemistry students, educators, and researchers interested in molecular bonding, particularly those studying isoelectronic species and molecular orbital theory.

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How and why do isoelectronic species have the same bond order? My book cites an example that says that F2 and O2 -2 (oxygen molecule ion) has a bond order of 1. I understand how fluorine gas has a bond order of 1. But how does the oxygen molecule ion have a bond order of 1? Is it because they both have the same number of valence electrons?
Thanks!
 
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You can calculate bond order using Molecular orbital theory.
Bond Order = [(number of electrons occupying bonding orbitals)-(number of electrons in anti-bonding orbitals)]/2
Try to find the bond order of ##O_2##, ##{O_2}^-## and ##{O_2}^{2-}## yourself.
 
Titan97 said:
You can calculate bond order using Molecular orbital theory.
Bond Order = [(number of electrons occupying bonding orbitals)-(number of electrons in anti-bonding orbitals)]/2
Try to find the bond order of ##O_2##, ##{O_2}^-## and ##{O_2}^{2-}## yourself.
Is there any other way to work it out? I haven't learned anti-bonding yet.
 
Its not a difficult concept. Refer some standard inorganic chemistry textbooks for MOT.
 

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