Calculate Ionic Strength of Ca2+ in 0.01M CaCO3 Solution

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SUMMARY

The ionic strength of Ca2+ in a 0.01M CaCO3 solution is calculated using the formula u=0.5 sum(Mi)(zi)^2. When calculating the ionic strength, it is essential to include all species present in the solution, including CO3^2-. The correct calculation, including both Ca2+ and CO3^2-, yields an ionic strength of 0.04M, while excluding CO3^2- results in an ionic strength of 0.02M. It is important to note that ionic strength is a property of the entire solution rather than individual ions.

PREREQUISITES
  • Understanding of ionic strength and its significance in solutions
  • Familiarity with the equation for calculating ionic strength
  • Knowledge of the charges of common ions, specifically Ca2+ and CO3^2-
  • Basic chemistry concepts related to solution concentrations
NEXT STEPS
  • Study the derivation and applications of the ionic strength formula in solution chemistry
  • Learn about the role of ionic strength in chemical equilibria and reaction rates
  • Explore the effects of ionic strength on solubility and precipitation reactions
  • Investigate how to calculate ionic strength for multi-ion solutions using software tools
USEFUL FOR

Chemistry students, researchers in analytical chemistry, and professionals working with solutions in laboratory settings will benefit from this discussion.

higherme
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Calculate the ionic strength of Ca2+ in a 0.01M CaCO3 solution.

equation to use is:

u=0.5 sum(Mi)(zi)^2
where M is the concentration and z is the charge of the species

my question is when I am calculating the ionic strength of Ca2+, do I have to include
CO3^2- that is in that solution?

so, it would be :

U=0.5 (0.01M Ca2+)(2+)^2 + (0.01M CO3^2-)(2-)^2
U=0.04M

if I don't include:
U=0.5 (0.01M Ca2+)(2+)^2
U=0.02M
 
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higherme said:
Calculate the ionic strength of Ca2+ in a 0.01M CaCO3 solution.
The question is meaningless to me. The ionic strength is defined for the entire solution, not for individual species.

As meaningless as it may be, it appears that the questioner what's you to calculate the contribution of Ca2+ alone (your second calculation). But this is just my interpretation of intent.

If you get a chance, please inform the person that wrote this question that ionic strength is not defined for individual species. If this is from a book, please cite the title, author, edition and page number.
 

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