How to Calculate the Madelung Constant for an Octahedral Arrangement?

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SUMMARY

The discussion focuses on calculating the Madelung constant for an octahedral arrangement of doubly charged anions surrounding a doubly charged cation. The key equations referenced include EA=-(Mke2)/r0 and α=2M/((n1+n2)|Z1Z2|). Participants emphasize that the Madelung constant is derived from summing the electrostatic interactions between ions, and one user seeks clarification on the equations used in their textbook, specifically from "Introduction to Solid State Physics" by Charles Kittel.

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  • Understanding of Coulomb's law and electrostatic interactions
  • Familiarity with the concept of Madelung constant
  • Knowledge of coordination numbers in ionic structures
  • Basic proficiency in mathematical summation techniques
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  • Study the derivation of the Madelung constant in ionic crystals
  • Learn about the electrostatic potential energy in ionic arrangements
  • Explore the application of Coulomb's law in solid-state physics
  • Review "Introduction to Solid State Physics" by Charles Kittel for relevant equations
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Homework Statement


Calculate the Madelung constant for an octahedral arrangement of doubly charged anions about a doubly charged cation. Use r0 for the anion−cation distance. (Hint: Remember that the Madelung constant considers the sum of Coulomb interactions over all atom/ion pairs).


Homework Equations



Possibly helpful Equations
EA=-(Mke2)/r0

α=2M/((n1+n2)|Z1Z2|)

EA=-(ke2α(n1+n2(|Z1Z2)/2r0

The Attempt at a Solution



So we have a theoretical bond pair X+2Y-2 with a coordination number of 6.

I believe the next step should be to calculate EA, but I fail to see how to do that without α.
 
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Your Madelung equation doesn't seem familiar to me, what textbook are you using?
 
Here is a screenshot of my professors notes I took these equations from.

Notes_zps8f083b95.jpg


This is our book:

https://www.amazon.com/dp/0521651514/?tag=pfamazon01-20

What equations would you have used?
 
Last edited by a moderator:
None of these. Madelung constant is calculated just by summing electrostatic interactions between ions.
 

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