Calculating 0.5M NaCl in 500mL Water

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Discussion Overview

The discussion revolves around calculating the amount of NaCl needed to prepare a 0.5M solution in 500mL of water. It includes aspects of molarity, solution preparation, and the relationship between moles and volume.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant attempts to calculate the grams of NaCl needed by stating that 1M corresponds to 58.5g in 1L, leading to a conclusion of 27.25g for 0.5M in 0.5L.
  • Another participant challenges the initial calculation, asserting that 0.5 moles in 0.5L does not equate to a 0.5M solution.
  • There is a question raised about whether the number of moles of NaCl changes with the amount of water used.
  • A later reply clarifies the relationship between moles and volume, suggesting a formulaic approach to determine the number of moles in a 0.5L solution.
  • Another participant emphasizes the correct terminology, stating that it should be "number of moles of NaCl" rather than "number of moles in NaCl."

Areas of Agreement / Disagreement

Participants express disagreement regarding the initial calculation of grams needed for the solution, and there is confusion about the terminology related to moles and volume. The discussion remains unresolved with multiple competing views on the correct approach.

Contextual Notes

There are limitations in the clarity of the initial calculations and the definitions used regarding moles and their relationship to solution volume.

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Homework Statement


How many grams of NaCl (molecular weight=58.5g mole^-1) would you dissolve in water to make a 0.5M NaCl solution with 500mL final volume?



Homework Equations





The Attempt at a Solution

Since, 1 L of 58.5g NaCl is equal 1M I used this to firstly convert 500ml into liters which is 0.5L and then I said that half 0f 58.5g is 27.25g NaCl and this will give me 0.5 M in 0.5L of water.
 
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No, 0.5 mole in 0.5L is not 0.5M.
 
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So, does the number of moles in NaCl change depending on the amount of water?
 
mmedin01 said:
So, does the number of moles in NaCl change depending on the amount of water?

[STRIKE]Yes.[/STRIKE] (Misread that "moles in NaCl"...)
Here's one way to look at it:

0.5 M NaCl = 0.5 mol NaCl/1 L solution = ? mol NaCl/0.5 L solution

For the two fractions to be equal, what number does the numerator have to be?
 
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mmedin01 said:
So, does the number of moles in NaCl change depending on the amount of water?

There is no such thing as "number of moles in NaCl". There is either "number of moles of NaCl" or "number of moles of NaCl in the given volume of the solution".
 
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