How to calculate the solubility of AgCl in a solution containing NaCl?

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Discussion Overview

The discussion revolves around calculating the solubility of AgCl in a solution containing NaCl, focusing on the common ion effect and the application of the solubility product constant (Ksp). Participants are examining the steps taken to arrive at a solution, including the use of an ICE table and the assumptions made during calculations.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant outlines the equilibrium reaction for AgCl and sets up an ICE table to analyze the solubility in the presence of NaCl.
  • There is a discussion about the common ion effect, where the presence of Cl- from NaCl is noted to affect the solubility of AgCl.
  • Participants question the molar mass of AgCl used in the calculations, with one participant stating they used 144 g/mol.
  • Another participant confirms the calculated solubility of AgCl as 1.2 x 10^-8 mol/L but suggests that the final result in grams may be incorrect.
  • One participant emphasizes the importance of the steps taken in the calculation rather than just the final result.
  • There are multiple confirmations of the calculated value of 1.8 x 10^-6 g/L, but disagreement exists regarding its correctness.
  • Participants express a need for advice on the approach to solving such problems, indicating uncertainty in the methodology.

Areas of Agreement / Disagreement

Participants generally agree on the steps taken to calculate the solubility but disagree on the accuracy of the final result. There is no consensus on the correctness of the calculations or the molar mass used.

Contextual Notes

Some participants suggest rechecking the molar mass of AgCl, indicating potential discrepancies in the calculations. The discussion highlights the dependency on assumptions made regarding the negligible value of x in the equilibrium expression.

brake4country
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Homework Statement


What mass of AgCl will dissolve in 1 L of water containing 0.0144 moles of NaCl. Ksp = 1.7 x 10^-10

Homework Equations


Ksp = [x][x] and ICE table

The Attempt at a Solution


So, the common ion effect is taking place here and the equilibrium taking place is:
AgCl(s) ↔ Ag+ + Cl-

Since excess Cl- will be present from the NaCl, the Na+ is just a spectator ion.

ICE table:
AgCl(s) ↔ Ag+ + Cl-
x 0 0.0144 M
-x x x
0 x 0.0144 + x

Ksp = [Ag+][Cl-] = 1.7 x 10^-10

(x)(0.0144 + x) = 1.7 x 10^-10

I assume that I can eliminate the x in the parentheses because it would be very small, thus:
0.0144x = 1.7 x 10^-10
x = 1.2 x 10^-8 mol/L
Converting to grams gives me 1.8 x 10^-6 g/L

I was wondering if someone wouldn't mind checking to see if my steps are accurate. Thanks in advance!
 
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What have you used for molar mass of AgCl? I got a slightly different result.
 
I used 144 g/mol. I will recheck my math.
 
Yes, x = 1.2x10^-8 mol/L
Thus, (1.2x10^-8 mol/L)(144 g/L) = 1.8x10^-6 g/L
 
brake4country said:
(1.2x10^-8 mol/L)(144 g/L) = 1.8x10^-6 g/L

No matter how many times you will write it, it won't get correct. Sorry.
 
Wait! The steps are more important! Can I get any advice on how I am approaching these problems?
 
Your approach is OK, the final result is not.
 
Borek is right, recheck your formula wt.
 

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