Calculating Entropy Changes in a Rigid Tank with Argon at Different Temperatures

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Homework Help Overview

The discussion revolves around calculating entropy changes in a rigid tank containing argon gas as it cools from an initial temperature of 200°C to a thermal reservoir at 0°C. The problem involves concepts from thermodynamics, specifically relating to internal energy, heat transfer, and entropy changes.

Discussion Character

  • Exploratory, Assumption checking

Approaches and Questions Raised

  • Participants discuss the calculation of the tank's volume using the ideal gas law and the change in entropy using the heat transfer equation. There is uncertainty regarding the final temperature of the argon and whether it can be assumed to be the same as the reservoir's temperature.

Discussion Status

The discussion is active, with participants exploring different interpretations of the final temperature of the argon and the implications of the thermal reservoir's properties. Some guidance has been offered regarding the assumption of constant temperature in thermal reservoirs, but no consensus has been reached on the final temperature of the argon.

Contextual Notes

Participants are navigating assumptions about heat exchange and the behavior of gases in thermal equilibrium, with specific attention to the implications of the reservoir's temperature on the argon's final state.

cmilho10
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A rigid tank of small mass contains 50.0 g of argon, initially at 200°C and 100 kPa. The tank is placed into a reservoir at 0°C and is allowed to cool to thermal equilibrium. Calculate the following:
(a) the volume of the tank
(b) the change in internal energy of the argon
(c) the energy transferred by heat
(d) the change in entropy of the argon
(e) the change in entropy of the constant-temperature bath

I got the volume of the tank from PV=nRT to be 49.2 L which is correct

change in entropy=dQr/T

Change in Eint=Q-W

I'm not sure where to go from here because I do not know how to find the final temperature of the argon.
 
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you stated in your question that you let it cool to 0 degrees... i think that's the final temprature of the argon...
 
It says that the reservoir is at 0 degrees, so I didn't think that would necessarily be the final temperature of the argon cause I thought some of the heat from the argon would be exchanged as well...but maybe I am totally wrong here
 
If it's a thermal reservoir, then the temperature is assumed to remain constant.
 

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