Calculating Percentage of Stannous Fluoride in Toothpaste Sample

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Discussion Overview

The discussion revolves around calculating the percentage of stannous fluoride (SnF2) in a toothpaste sample based on the mass of precipitate formed (stannous phosphate). Participants explore the stoichiometric relationships in the chemical reaction and how to apply them to find the desired percentage.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant suggests using the formula for percentage composition, indicating a need to calculate the theoretical yield of stannous fluoride based on stoichiometry.
  • Another participant advises starting from the mass of the precipitate and emphasizes the importance of balancing the reaction to determine mole ratios.
  • A participant clarifies their understanding of the problem, noting that the total mass of the toothpaste sample includes both reactants and that they need to convert the precipitate to moles to find the mass of stannous fluoride.
  • Another participant reinforces the idea that only a portion of the 10g sample is stannous fluoride and highlights the need to determine what proportion of the sample was SnF2.
  • One participant expresses their understanding of using the molar ratio to relate the product back to the reactant for the percentage calculation.

Areas of Agreement / Disagreement

Participants generally agree on the approach to solving the problem, focusing on stoichiometry and the relationship between the precipitate and the original sample. However, there is some clarification needed regarding the interpretation of the total mass of the sample and its relation to the reactants.

Contextual Notes

There is an assumption that participants are familiar with stoichiometric calculations and the concept of theoretical versus actual yield. The discussion does not resolve the specific calculations or provide a definitive answer to the percentage of stannous fluoride.

Who May Find This Useful

This discussion may be useful for students working on chemistry problems involving stoichiometry, particularly in the context of determining the composition of mixtures based on precipitate formation.

QuarkCharmer
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Homework Statement


A 10.000g sample of toothpaste containing stannous fluoride gives a 0.145g precipitate of stannous phosphate. What is the percentage of SnF_2 in the toothpaste sample?

Homework Equations



(Actual yield)/(Theoretical yield) * 100%

3SnF_{2}_{(aq)} + 2K_{3}PO_{4}_{(aq)} \rightarrow Sn(PO_{4})_{2}_{(s)} + 6KF_{(aq)}

The Attempt at a Solution



I am not positive what they are asking here. I understand that they want me to use the above formula (the percent one) to find the % composition of a certain molecule in the substance. I am thinking that they want me to first use the 10.000g to calculate the theoretical yield of the stannous fluoride using basic stoichometry and then divide the given mass of product (the precipitate) by that to get a number as a percent. Is that the correct approach?

Thanks

Edit, something is up with the LaTeX here, there should be a formula for calculating the percent (X/Y *100%) and the chemical equation, i don't know why it's rendering like it is with 2 of the chemical formulas. If you click the top equation you will see what I mean.
 
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The question has no complications. Start working backward from the mass of precipitate. Be sure to balance the reaction and then you will have mole ratios from this.
 
Ah, I see what you mean. The 10.000g is the total of both the reactants on the left side of the EQ. So I start with the precipitate, convert to moles, then use a mole ratio to get that in terms of the desired molecule, and convert back to grams using that mass over the 10.000 grams to form the percent equation.

For some reason I kept thinking of the 10.000g as the starting value, probably because every other problem we have done is formed that way.

Thanks a lot!
 
Most of what you say is correct. Be sure you understand that most of your 10 gram sample IS NOT THE REACTANTS; only some of it is. The question asks essentially, what proportion of the 10 grams sample of toothpaste was stannous fluoride?
 
I get that, so when I work the product out to using the molar ratio to the questioned reactant, I would put the reactant over the whole mass of the product side. In this case over 10 grams to get the percent. Thanks
 

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