Calorimetry Calibration: Find qrxn, qcal, and Ccal with NaOH and HCl

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SUMMARY

The discussion focuses on calculating the heat exchange (qrxn) and calorimetry constants (Ccal) in a reaction involving 10 mL of 1M NaOH and 5 mL of 1M HCl with a temperature change of 2.1°C. The key equations used are qrxn = -qcal and Ccal = qcal/∆T. Participants emphasize the importance of using the known volumes and concentrations to derive the necessary values, highlighting that the density of the solution can be assumed to be 1 g/mL for calculations. This provides a complete framework for solving the calorimetry problem.

PREREQUISITES
  • Understanding of calorimetry principles
  • Familiarity with the concept of heat exchange (qrxn and qcal)
  • Knowledge of molarity and concentration calculations
  • Basic skills in using temperature change (∆T) in thermodynamic equations
NEXT STEPS
  • Calculate qrxn using the provided volumes and concentrations of NaOH and HCl
  • Determine qcal by applying the equation qrxn = -qcal
  • Compute Ccal using the formula Ccal = qcal/∆T
  • Explore the assumptions in calorimetry, such as density approximations for dilute solutions
USEFUL FOR

Chemistry students, educators, and laboratory technicians involved in thermodynamics and calorimetry experiments will benefit from this discussion.

liwolf
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Homework Statement


in the reaction 10mL of 1M NaOH + 5mL of 1M HCl (adiabatic)
given change in temp=2.1°C (temp initial is the temp of NaOH, temp final is acquired after the addition of HCl)
find: qrxn, qcal, Ccal


Homework Equations


qrxn = -qca
Ccal = qcal/∆T


The Attempt at a Solution


sorry but I'm really at total lost here. i took the prerequisite chemistry 4semesters ago
the only thing that i can find in searching are the formula on how to solve them but i can't quite get how to use those given only the dT
 
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You are given much more - you know the volumes, you know concentrations (that gives amounts of acid and base), assuming density of 1 g/mL (often done for not too concentrated water solutions) you have also total mass. Plenty of data to solve the question.
 

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