One to one and onto? Onto what? If I were talking about a function with domain between 0 and 1 and said it was "onto" the reasonable assumption would be it was "onto" (0, 1). The function y= x does that nicely!
As for a function that is one-to-one and onto from (0, 1) to the set of all real numbers, I would think a variation on tan(x) would work nicely. tan(x) covers all real numbers for x between [itex]-pi/2[/itex] and [itex]\pi/2[/itex] so [itex]f(x)= tan(-\pi/2+ \pi x)[/itex] should work nicely: when x= 0, [itex]-\pi/2+ \pi (0)= -pi/2[/itex]. When x= 1, [itex]-pi/2+ \pi (1)= \pi/2[/itex]. Unless I have misunderstood what you are looking for, that should be exactly what you want.