Can nitrous oxide be made from air?

  • Thread starter Thread starter Stormer
  • Start date Start date
  • Tags Tags
    Air
Click For Summary
SUMMARY

The discussion centers on the feasibility of producing nitrous oxide (N2O) directly from atmospheric nitrogen and oxygen without additional chemicals, aside from catalysts. It is established that natural processes, such as lightning, contribute to N2O formation, but these do not provide a practical method for direct synthesis. The most viable route identified involves electrolyzing water to produce hydrogen, followed by the Haber-Bosch process to create ammonia, which can then be oxidized to form N2O. However, this method is deemed inefficient and complex, highlighting the challenges in achieving direct N2O production from air.

PREREQUISITES
  • Understanding of the Haber-Bosch process for ammonia synthesis
  • Knowledge of electrolysis for hydrogen production
  • Familiarity with nitrous oxide (N2O) chemical properties and reactions
  • Awareness of atmospheric chemistry, particularly the role of ozone
NEXT STEPS
  • Research the efficiency and advancements in the Haber-Bosch process
  • Explore methods for optimizing electrolysis for hydrogen production
  • Investigate alternative catalysts for direct N2O synthesis
  • Examine the environmental impact of nitrous oxide emissions and production
USEFUL FOR

Chemists, environmental scientists, and engineers interested in atmospheric chemistry, nitrogen cycle processes, and sustainable methods for nitrous oxide production.

Stormer
Messages
121
Reaction score
22
The air is full of nitrogen and oxygen but can this somehow be reacted together to make N2O without any other chemicals involved (other than as a catalyst or other non consumable role)?
 
Chemistry news on Phys.org
Lightning?
 
  • Like
Likes   Reactions: Astronuc and TeethWhitener
Stormer said:
The air is full of nitrogen and oxygen but can this somehow be reacted together to make N2O without any other chemicals involved (other than as a catalyst or other non consumable role)?
What has your research told you about how N2O is produced, whether naturally or artificially? Did you find any that do not involve intermediate steps?
 
  • Like
Likes   Reactions: Astronuc, bigfooted, jim mcnamara and 2 others
Stormer said:
The air is full of nitrogen and oxygen but can this somehow be reacted together to make N2O without any other chemicals involved (other than as a catalyst or other non consumable role)?
Why would one want to do that?

https://cfpub.epa.gov/si/si_public_record_report.cfm?Lab=NRMRL&dirEntryId=129929

Stormer said:
Does that not mostly just make ozone?

The origin of nitrous oxide in the atmosphere is due to the reaction between nitrogen molecules and oxygen atoms formed by the photochemical dissociation of ozone in the atmosphere.
https://journals.aps.org/pr/abstract/10.1103/PhysRev.95.320 (received: 1954; published: 1955)

Stormer said:
Do you really think that is a good answer to my question?
Seems like a good answer. A link is provided for one's edification.
 
The triple bond between the two nitrogen atoms in N2 is the second strongest covalent bond there is. The C-O bond in carbon monoxide is slightly stronger.

Nitrogen is a very stable compound. Around about the end of the 19th century, there was concern that, by the 1920s, widespread starvation would break out.

The problem was that there was not enough nitrogen-containing fertilizers to grow enough wheat to feed the increasing world population. What was needed was a catalyst that would speed up

N2 + 3H2 ----> 2NH3 (ammonia) Once you have NH3, it's easy to make fertilizers (or explosives)

Today about 50% of the nitrogen atoms in our bodies come from this reaction.

There is a wonderful book on all this

https://www.amazon.com/dp/0307351793/?tag=pfamazon01-20
 
Last edited by a moderator:
  • Informative
Likes   Reactions: berkeman
Diesel engine fixes atmospheric nitrogen - unfortunately.
 
DaveC426913 said:
What has your research told you about how N2O is produced, whether naturally or artificially? Did you find any that do not involve intermediate steps?
Not much.
The "best" route i found that does not involve other chemicals than those that is readily available everywhere (water and air) is to first elektrolyse water to hydrogen, then make ammonia with the haber bosch process, and then make the N2O by oxidation of the ammonia.

But this route is really inefficient and complex.

That is why i am asking here obviously.

Astronuc said:
Why would one want to do that?
To make N2O without having to get other chemicals to do it. For example to make it just using energy and the resources available offshore on a boat.
Astronuc said:
The origin of nitrous oxide in the atmosphere is due to the reaction between nitrogen molecules and oxygen atoms formed by the photochemical dissociation of ozone in the atmosphere.
So is there a way to do this efficiently and to separate out the N2O with a machine?
Astronuc said:
Seems like a good answer. A link is provided for one's edification.
I am obviously not asking for N2O as a trace gas byproduct of another process. I am asking about how you can produce N2O from fluids that is readily available everywhere (like air and water). So no that is not a good answer at all.
 
Last edited:
  • #10
Stormer said:
But this route is really inefficient and complex.
That's a bit shifting the goal post. You asked whether it is doable - yes, it is. mjc123 signaled the most obvious natural way in the first post, you listed one in your own post. Now you are asking a different question, one about the process economy. My bet is that no, there are no known more efficient ways than the one you listed, otherwise they would long replace the Haber-Bosh process and its variants (once you have any nitrogen oxide converting it into other nitrogen compounds is relatively simple, it is the initial reaction involving breaking of the triple bond that is the difficult step).
 
  • Like
Likes   Reactions: Bystander

Similar threads

Replies
4
Views
2K
Replies
19
Views
4K
Replies
3
Views
2K
  • · Replies 1 ·
Replies
1
Views
877
  • · Replies 17 ·
Replies
17
Views
4K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 22 ·
Replies
22
Views
3K
  • · Replies 46 ·
2
Replies
46
Views
6K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K