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Horizontal polarization $|\leftrightarrow>=\binom{1}{0}$

Vertical polarization $|\updownarrow>=\binom{0}{1}$

The density matrix in this problem is:

$$\rho =\frac{1}{2}\begin{pmatrix}

1+\xi _{1} & \xi_{2}-i\xi _{3}\\

\xi_{2}+i\xi _{3} & 1-\xi _{1}

\end{pmatrix}$$

The Stokes parameters are: $\xi _{1}, \xi _{2}, \xi _{3}$

The probability that if the photon has got lineal polarization whose axis forms an angle $\theta$ with de horizontal is:

$$|w>=cos\theta |\leftrightarrow>+sin\theta|\updownarrow>$$

$$ P_{\theta}=<w|\rho|w>=\frac{1}{2}\left ( 1+\xi_{1}cos(2\theta)+\xi_{2}sin(2\theta) \right )$$

Is there any value of the [Stokes parameters](http://en.wikipedia.org/wiki/Stokes_parameters) for which this probability is zero?