Can we write mass in coefficients of elements in a chemical equation

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SUMMARY

The discussion centers on the representation of chemical reactions in terms of mass, specifically using the equation CH4 + 2O2 -> CO2 + 2H2O. Participants confirm that while it is possible to express the reaction using mass (e.g., 16g CH4 + 64g O2 -> 44g CO2 + 36g H2O), this method lacks the ability to verify the conservation of atoms and moles. The consensus is that mass representation is valid but cannot ensure the accuracy of the reaction without considering atomic and molecular quantities.

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SHASHWAT PRATAP SING
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let's take a chemical equation - CH4+2O2 ------> CO2+2H2O
From Reactant side- the coefficient of CH4 is 1 and the coefficient of O2 is 2
From Product side - the coefficient of CO2 is 1 and the coefficient of H2O is 2
we can write this chemical equation in terms of molecules,atoms,moles.
Can we write this chemical equation in terms of mass as-
16g of CH4 reacts with 2✕ 32g of O2 to give 44g of CO2 and 2✕18g of H2O.
So, can we write this chemical equation as- 16gCH4 + 64gO2 ------> 44gCO2 + 36gH2O
Please Help Me...
 
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SHASHWAT PRATAP SING said:
let's take a chemical equation - CH4+2O2 ------> CO2+2H2O
From Reactant side- the coefficient of CH4 is 1 and the coefficient of O2 is 2
From Product side - the coefficient of CO2 is 1 and the coefficient of H2O is 2
we can write this chemical equation in terms of molecules,atoms,moles.
Can we write this chemical equation in terms of mass as-
16g of CH4 reacts with 2✕ 32g of O2 to give 44g of CO2 and 2✕18g of H2O.
So, can we write this chemical equation as- 16gCH4 + 64gO2 ------> 44gCO2 + 36gH2O
Please Help Me...
Yes.
 
Yes, that's one of a correct ways of expressing mass conservation.

However, there is no way to balance such equation. When you write

CH4 + 2O2 -> CO2 + 2H2O

you can easily check, that no atoms were created nor destroyed in the process. As we know masses of atoms (and/or moles) that in turn defines the ratio of amounts of reactants and products. When the equation is written using masses alone you can't check if the ratio is correct.
 
Borek said:
However, there is no way to balance such equation. When you write
If there is no way to balance such equation.
Would this chemical equation be correct -
16gCH4 + 64gO2 ------> 44gCO2 + 36gH2O
 
It is OK as written, but there is no way to prove it without thinking in terms of atoms and moles.

It is easy to check that

CH4 + 2O2 -> CO2 + 2H2O

is OK - atoms (and charges, even if they are not listed) are conserved. Just count them on both sides of the equation.

It is also easy to show that

CH4 + 2O2 -> CO2 + H2O

is incorrect - there are two hydrogen atoms and one oxygen atom missing on the right.

But you can't tell whether

10 g CH4 + 33 g O2 -> 32 g CO2 + 11 g H2O

is OK or not, unless you do calculations using moles and molar masses.
 
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