Can you DIY thermoform Viton sheets?

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Discussion Overview

The discussion centers around the feasibility of DIY thermoforming Viton sheets, exploring whether Viton behaves like a thermoplastic that can be reshaped with heat or if it is more akin to thermoset materials that cannot be reformed after curing. Participants examine the properties of Viton, its processing methods, and potential alternatives for creating custom gaskets.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • Some participants note that Viton is typically pressure molded or injection molded and question if it can be vacuum formed after heating, similar to thermoplastics.
  • One participant cites a source indicating that Viton does not flow when heated to high temperatures, suggesting it behaves like a thermoset material that cannot be reshaped once cured.
  • Another participant mentions that overheated elastomer seals develop more cross-links, leading to increased hardness and brittleness, which could compromise sealing effectiveness.
  • A participant inquires about the availability of uncured Viton for DIY applications, expressing interest in creating custom high-temperature gaskets.
  • One response discusses the complexity of casting equivalent elastomers and suggests exploring two-part kits from resin suppliers as an alternative to Viton.
  • A participant shares their specific application for Viton in making rolling diaphragm seals for a Stirling motor, expressing concerns about the heat resistance of alternative materials like silicone.

Areas of Agreement / Disagreement

Participants generally agree that Viton behaves more like a thermoset material, but there is no consensus on the availability of uncured Viton or the suitability of alternative materials for specific applications.

Contextual Notes

Participants express uncertainty regarding the processing of Viton, the implications of heating on its properties, and the challenges of sourcing appropriate materials for DIY projects. There are also unresolved questions about the performance of alternative materials under specific conditions.

Stormer
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Viton rubber is pressure molded with heat or injection molded to form complex gaskets from what i have read. But do it behave like a thermoplastic where you can for example buy a sheet of finished Viton rubber, heat it up and then vacuum form it to the shape you want? Or is it more like thermoset resins where you can not heat it up and form it again after it has been done one time?
 
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Here is the answer you don't want: "Maybe"

A Google search
(https://www.google.com/search?&q=softening+temperature+Viton)
returned many results for processing, usage, and cautions.

The first search hit was:
https://www.google.com/url?esrc=s&q...YQFXoECAUQAg&usg=AOvVaw1PSw6Q55Ua7EnV4qRM8WbR

Which states that the curing agent should be mixed with the fillers then added to the polymer. It also refers to the curing as "vulcanizing."

The document closes with:
"For more information, visit Viton.com"
 
"Viton seals provide an indefinite seal for temperatures up to 400°F, and for temperatures up to 600°F they offer an excellent seal for more than 48 hours."
https://www.humphrey-products.com/news/viton-vs-buna-which-seal-for-your-applications
Which tells you that Viton does not flow when heated up to 600°F.

Stormer said:
But do it behave like a thermoplastic where you can for example buy a sheet of finished Viton rubber, heat it up and then vacuum form it to the shape you want?
You cannot change the shape of cured Viton by heating it.

In general, elastomer seals that are overheated develop more cross-links, so they become harder and more brittle. With Viton, that begins to happen slowly above 400°F, then rapidly above 600°F. Being less flexible results in a poor seal that may fracture, or will not remain compliant with the surfaces of the gaps it is sealing.
 
Ok. So i guess it is more like a thermoset material. Is there anywhere for a DIY'er where you can buy Viton that is not cured so you can make your own custom shaped high temperature gaskets?
 
https://www.martins-rubber.co.uk/blog/what-is-viton-our-essential-guide/
Write ... "Viton® is a brand name of DuPont for its synthetic rubber and fluoropolymer elastomer, commonly used in O-rings and other moulded or extruded products. This family of elastomers comprises copolymers of terpolymers of tetrafluoroethylene (TFE), hexafluoropropylene (HFP) and vinylidene fluoride (VDF or VF2), vinylidene fluoride (VDF) and hexafluoropropylene (HFP) as well as perfluoromethylvinylether (PMVE) containing specialty polymers".

To cast your own equivalent elastomers will be difficult because you will need to blend the components to get the required final chemical and mechanical properties.

You may be able to buy a two part kit from a resin supplier, or from a DuPont agent.

I would want to check first why you need to use a "Viton® like" polymer, and why a two part silicone compound would not be a much easier material to obtain, cast and cure. What are you trying to make, and why must it use Viton®.
 
Baluncore said:
I would want to check first why you need to use a "Viton® like" polymer, and why a two part silicone compound would not be a much easier material to obtain, cast and cure. What are you trying to make, and why must it use Viton®.
I want to make some rolling diaphragm seals for a pressurized Stirling motor so i don't have to pressurize the crankcase. So the material needs to be both heat resistant and relatively strong (it will be backed up with pressurized oil). Maybe silicone will work if i get a hard enough type? But i don't think the really soft type of silicone i have usually seen will work for this.

It will be in the cold side of the cylinder, but still i don't think normal thermoplastic elastomers like the flexible 3D printer filaments are made of will take the heat the "cold side" can get up to without softening to much and failing.
 
Last edited:

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