Carbon dioxide from an antacid tablet

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SUMMARY

The discussion centers on the impact of a wet flask on the measurement of carbon dioxide (CO2) released during the reaction of calcium carbonate (CaCO3) with hydrochloric acid (HCl). It is established that a wet flask does not increase the total CO2 released; rather, it can lead to premature gas evolution, resulting in lower measured concentrations of CaCO3. The calculations provided illustrate that if only 1g of CO2 is collected instead of the expected 44g, the concentration of CaCO3 would be underestimated, confirming that the wet flask scenario leads to a negative error in concentration measurement.

PREREQUISITES
  • Understanding of stoichiometry in chemical reactions
  • Familiarity with the reaction of calcium carbonate with hydrochloric acid
  • Knowledge of gas collection methods in laboratory settings
  • Basic principles of pressure and temperature measurements in chemistry
NEXT STEPS
  • Study the stoichiometric calculations for gas evolution reactions
  • Research methods for accurately measuring gas volumes in chemical experiments
  • Explore the effects of environmental factors on gas collection in laboratory settings
  • Learn about the principles of error analysis in experimental chemistry
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Chemistry students, laboratory technicians, and educators involved in teaching chemical reactions and gas measurement techniques will benefit from this discussion.

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Homework Statement


Let’s say the % concentrations of CaCO3 (table 5) you obtain from trial #1 and #2 are consistent, while the concentration obtained from trial #3 is significantly higher. Demonstrate, how and where, a wet flask could be involved to explain such a result. Explain in great details.

Homework Equations


The equations under Calculations
https://docs.google.com/open?id=0By9VwoUlJRdCMzgxYjM1YzQtODA3MS00YmM5LWJiNjYtYmRlNDUwNDNjYTI3

The Attempt at a Solution


Alright, so we did a lab with calcium carbonate and antacid today, reacting each with HCl and measuring the pressure/temperature before the reaction and then after the reaction. From this we can find the volume, amount, mass, etc. I have no idea as to how to approach this question, it seems as it wouldn't depend on whether the flask is wet or not - because a wet flask with release more CO2 but how does that contribute to the final concentration of calcium carbonate in an antacid tablet? Any hints would be appreciated.
 
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Wet flask will not release MORE CO2. CO2 will start evolving before you start to collect it, so you will not collect everything.

Imagine you collected all of the gas and it was 44g of CO2 - how much CaCO3 was present?

Now imagine gas started to evolve too early and instead of 44g you collected only 1g. Use the same stoichiometry to calculate how much CaCO3 was present. Is it a positive, or negative error?
 
There would be a LOWER concentration of CaCO3 then! So the answer to the question would be NO, because if anything it would be a lower a concentration? Of course I have to back that up with reasoning + stoich. To answer your question, there would be 1g of CaCO3. What do you mean by positive/negative error?
 
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