Calcium Carbonate in Antacid: Why Higher Yield in Wet Flask?

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Discussion Overview

The discussion revolves around the determination of calcium carbonate concentration in antacid tablets, specifically exploring why a wet flask setup results in a higher yield of gas during the reaction with hydrochloric acid (HCl). The scope includes experimental methods and gas laws.

Discussion Character

  • Experimental/applied, Technical explanation

Main Points Raised

  • One participant questions why a wet flask leads to a higher concentration of gas, suggesting that some calcium carbonate may react with water and escape, which they initially expect to lower the yield.
  • Another participant requests clarification on the method used to determine the concentration of calcium carbonate, indicating that the answer may depend on the specifics of the experimental setup.
  • A participant describes a reaction method involving HCl and calcium carbonate in an antacid, detailing the use of a pressure detector to measure gas production by calculating the difference in moles of gas before and after the reaction.
  • Another participant points out that the pressure sensor measures the total pressure of gases in the flask, emphasizing that it is more accurate to refer to the measurement as the partial pressure of CO2 and questions what other gases might be present.

Areas of Agreement / Disagreement

Participants have not reached a consensus, as there are differing views on the implications of using a wet flask and the specifics of the gas measurements involved.

Contextual Notes

The discussion highlights potential limitations in understanding the gas yield, including assumptions about gas composition and the effects of water on the reaction.

lmlgrey
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1. When determining the concentration of calcium carbonate in an antacid tablet, why using a wet flask will end up with a significant higher concentration?



2. Gas laws



I would expect a lower yeild of gas since some of the calcium carbonate reacts with water and escape from the tube...but higher??
 
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Can you describe the method that you are using? It's hard to answer without knowing how you determine the concentration of calcium carbonate.
 
A reaction happened between HCl and antacid (which contains calcium carbonate) and the reaction flask was equipped with a pressure detector... by calculating the difference between # of moles of gas in the flask before and after(nf-ni=(pf'/Tf-pi'/Ti)*V/R...
 
Your pressure sensor measures the pressure of every gas within the flask. It is more proper to say that you are measuring the partial pressure of CO2. What other gases are present in the flask?
 

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