Changing The Shape of a potential well

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SUMMARY

The discussion focuses on the transition of a particle from the first excited state of an infinite square well to the energy eigenstates of a harmonic oscillator after an abrupt change in potential shape. It is established that all odd states of the harmonic oscillator will be excited due to the initial odd state of the infinite well. The concept of abruptness is linked to the energy-time uncertainty principle, which dictates that the change must occur rapidly enough to prevent the system from evolving into a different state. The discussion also highlights that an instantaneous change does not alter the initial state but requires representation in the harmonic oscillator basis.

PREREQUISITES
  • Understanding of quantum mechanics, specifically potential wells and wave functions.
  • Familiarity with energy eigenstates and their significance in quantum systems.
  • Knowledge of the harmonic oscillator model in quantum mechanics.
  • Concept of the energy-time uncertainty principle and its implications.
NEXT STEPS
  • Study the decomposition of wave functions in quantum mechanics, focusing on infinite square wells and harmonic oscillators.
  • Research the energy-time uncertainty principle and its mathematical formulation.
  • Explore the concept of adiabatic processes in quantum mechanics and their effects on state transitions.
  • Examine examples of abrupt changes in quantum systems and their outcomes.
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Students and professionals in quantum mechanics, physicists studying wave function transitions, and anyone interested in the dynamics of quantum systems under potential changes.

dsr39
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This question was posed to me a while ago, but I never fully understood how to solve it.

You have a particle in the first excited state of the infinite square well (with the origin taken to be at the center. You "abruptly" change the shape of the potential well to be that of the harmonic oscillator and characterize the immediate result on the wave function

Which energy eigenstates of the harmonic oscillator are excited, and how quickly (roughly) must this change be made for it to be considered abrupt?

I think I see that ALL of the odd states of the harmonic oscillator should be excited since you were in an odd state of the infinite well, and I think classifying abrupt has something to do with the energy time uncertainty principle, but I am not sure what value to use for delta-E

Any help is much appreciated
 
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Well, in order to figure out which states of the harmonic oscillator are excited, you'd need to decompose the first excited state of the infinite square well in terms of harmonic oscillator eigenstates. So if |\psi_m\rangle is a square well eigenstate and |\varphi_n\rangle is a SHO eigenstate, any state for which \langle\psi_1|\varphi_n\rangle \neq 0 will be excited. Offhand I suspect that that's going to be true for all odd n (i.e. that your thought was correct).

Now, as for how quickly the change needs to be made: here's something interesting on Wikipedia, although I can't personally vouch for its correctness.
 
If the potential replacement is made instantly, your initial state |\psi_m\rangle does not change. You just have to represent it in a different basis (oscillator wave functions). I think the previous post explanation and Wikipedia reference are good for your purposes.

If you change slowly, you have the adiabatic invariant En/frequency, so the energy may change but no other excited stated will appear (they all will be of a very small amplitude).

Bob.
 

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