Chemistry:difficulty in understanding these statements:-

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Discussion Overview

The discussion revolves around the understanding of periodic trends in halogens, specifically regarding their oxidizing power and reactivity as one moves down Group 7 of the periodic table. Participants explore the definitions and implications of oxidation, the behavior of halogens as oxidizing agents, and the contrasting trends observed across periods.

Discussion Character

  • Conceptual clarification
  • Debate/contested
  • Technical explanation

Main Points Raised

  • One participant expresses confusion about the statement that the oxidizing power of halogens decreases down the group, questioning whether this refers to their ability to act as oxidizing agents.
  • Another participant notes that the normal oxidation state for halogens is -1, implying that they must gain an electron to achieve stability.
  • Definitions of oxidation are discussed, with one participant outlining that oxidation involves gaining oxygen, losing electrons, or losing protons, leading to an increase in oxidation number.
  • There is a reiteration that when one substance oxidizes another, it gains electrons, and the oxidizing agent is the one that facilitates this process.
  • Concerns are raised about the apparent contradiction between the decreasing oxidizing ability of halogens down the group and the increasing reducing ability across a period, leading to confusion about how these trends can coexist.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the interpretation of oxidizing power and its implications for periodic trends. Multiple viewpoints are presented, and the discussion remains unresolved regarding the relationship between the trends in reactivity and oxidizing ability.

Contextual Notes

Participants highlight the complexity of definitions related to oxidation and the need for clarity on how these definitions apply to different groups and periods in the periodic table. There are unresolved questions about the implications of these trends and how they interact.

leena19
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'As the atomic radius increases down Group 7 halogens,the ability to accept an electron decreases,(this, I understand).
As a result,the reactivity of halogens decreases down the group and also the oxidising power/ability of the halogens decreases down the group"

It is the part in bold that I can't understand.Does the oxidising power stated here refer to the elements' ability to act as oxidising agents?Atleast this is what I think, considering the Cl2 water test,but elsewhere ,my notes on the periodic trends state that across a period 'the reducing power/reducing ability infact,increases across a period'.
Now I'm confused,'cos if the first were true,that would mean the ability to undergo oxidation would increase across a period which seems a bit absurd,I think?

My other problem is, "down the electrochemical series the higher metals replace the lower ones,but for the non-metals in the series the reverse is true,the nonmetal lower down displaces the one higher",but how so,I tried googling but I didn't get a comprehensive answer.

Hope my problem is clear and I really hope someone can help me understand .
THANX IN ADVANCE
 
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The normal oxidation state for a halogen is -1... thus, the neutral atom must grab an electron from somewhere to achieve that electronic configuration.

What is the definition of oxidation?
 
Oxidation is when an atom,
1. gains oxygen
2.loses electrons
3.loses protons ? Thus the oxidation no. of the atom increases
 
When something oxidizes something else, it grabs electrons. The thing that supplied the electrons is oxidized and the thing that did the grabbing is reduced.
 
chemisttree said:
When something oxidizes something else, it grabs electrons. The thing that supplied the electrons is oxidized and the thing that did the grabbing is reduced.

Yes.I understand this.the thing that oxidises something else is an oxidising agent and that which underwent oxidation is a reducing agent.

But what I don't understand is,
the reactivity of halogens decreases down the group and also the oxidising power/ability of the halogens decreases down the group"
the meaning of the phrase 'oxidising ability/power' as used here.I think it means the elements' ability to act as an oxidising agent cause I believe Cl2 is a better oxidising agent than Br2,I2, which is the basis of the Cl2 water test,right? so...their ability to act as oxidisnig agents decreases down the group?
But if my interpretation of "oxidising ability/power' were true,
my notes on the periodic trends state that across a period 'the reducing power/reducing ability infact,increases across a period'.
how can this also be true?
This would mean that across a period ,the ability to undergo oxidation increases across a period?
I'm extremely confused.
Need some help here,please...
 

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