Chemistry, Equilibrium Constant Question

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SUMMARY

The discussion focuses on calculating the amount of NaOH required to create a buffer solution with a pH of 7.80 from 0.70 M HClO. The key calculation involves using the Henderson-Hasselbalch equation, which determines the ratio of the weak base (ClO-) to the weak acid (HClO). The derived ratio is 2.19, leading to the conclusion that 0.240 moles of NaOH must be added to achieve the desired buffer conditions.

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jaguar7
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Haha --- nvm, found it. Sorry/Thanks... ^_^

Where does the 2.19 come from?

How many moles of NaOH would need to be added to 500.0 mL of 0.70 M HClO to create a buffer with a pH of 7.80?

Initially, we have 0.35 mol of HClO. We are going to add NaOH which will react with the weak acid to create the conjugate weak base.

HClO + OH- → H2O + ClO-It is this weak base we’ll need to have for the buffer. First, let’s find the ratio of the weak base to the weak acid using the Henderson-Hasselbalch equation:

7.80 = -log(3.5*10^(-8) + log(base/acid)

base/acid = 2.19

Since we will be making base from the weak acid, we will react x moles of OH-. So after the reaction takes place, we have 0.35 – x moles of acid and x moles of base.

x / (0.35 - x) = 2.19

x = 0.240 moles
 
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